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Lee, Jae Sung
Eco-friendly Catalysis and Energy Lab
Research Interests
  • Photocatalytic water splitting, artificial photosynthesis, fuel cells, heterogeneous catalysis

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CHEMICAL-EQUILIBRIA IN METHANOL SYNTHESIS FROM METHYL FORMATE

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Title
CHEMICAL-EQUILIBRIA IN METHANOL SYNTHESIS FROM METHYL FORMATE
Other Titles
CHEMICAL-EQUILIBRIA IN METHANOL SYNTHESIS FROM METHYL FORMATE
Author
KIM, Kwang ManKIM, Jae ChangCHEONG, MinsekLee, Jae SungKIM, Young Gul
Issue Date
1990-10
Publisher
KOREAN INSTITUTE CHEMICAL ENGINEERS
Citation
KOREAN JOURNAL OF CHEMICAL ENGINEERING, v.7, no.4, pp.259 - 268
Abstract
The chemical equilibria of the gas-phase methanol production from methyl formate were studied by analyzing the hydrugenolysis reaction (HCOOCH3+ 2H2 -2CH3OH) and decarbonylation reaction (HCOOCH3 CH3OH + CO) occurring concurrently.The equilibrium constant, which includes the effects of nonideality, was estimated fur each reaction using equations of state. Equilibrium composition for each constituent in this reaction system was evaluated in relation to temperature, pressure, and initial concentration ratio (H2/HCOOCH3), and the effect of CO feed on equilibrium conversion of methyl formate was also discussed. General guidelines lo improve the selectivity of hydrogenulysis reaction were proposed. © 1990 Korean Institute of Chemical Engineering.
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DOI
10.1007/BF02707178
ISSN
0256-1115
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ECHE_Journal Papers
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