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Lee, Jae Sung
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Catalytic hydrodenitrogenation of indole over molybdenum nitride and carbides with different structures

Alternative Title
Catalytic hydrodenitrogenation of indole over molybdenum nitride and carbides with different structures
Author(s)
Li, SenziLee, Jae SungHyeon, TaeghwanSuslick, Kenneth S.
Issued Date
1999-08
DOI
10.1016/S0926-860X(99)00044-7
URI
https://scholarworks.unist.ac.kr/handle/201301/12714
Fulltext
http://www.sciencedirect.com/science/article/pii/S0926860X99000447#
Citation
APPLIED CATALYSIS A-GENERAL, v.184, no.1, pp.1 - 9
Abstract
The hydrodenitrogenation (HDN) of indole has been studied over Mo2N and Mo2C with different structures. The difference in activity was modest and the structure of the catalysts exerted a more significant effect than the chemical composition. More evident difference was observed in selectivity, and here the composition was the most important factor. Sonochemically prepared Mo2C was an active catalyst for HDN reaction. It formed plate-like aggregates of loosely packed Mo2C (fcc) particles. The crystallinity of sonochemically prepared Mo2C was improved during the reaction, and its behavior in HDN became similar to Mo2C (fcc) prepared by the TPR method. (C) 1999 Elsevier Science B.V. All rights reserved
Publisher
ELSEVIER SCIENCE BV
ISSN
0926-860X

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