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Lee, Jae Sung
Eco-friendly Catalysis and Energy Lab
Research Interests
  • Photocatalytic water splitting, artificial photosynthesis, fuel cells, heterogeneous catalysis

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THE SYNTHESIS OF ACETIC-ACID FROM METHYL FORMATE CATALYZED BY NICKEL-COMPLEXES

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Title
THE SYNTHESIS OF ACETIC-ACID FROM METHYL FORMATE CATALYZED BY NICKEL-COMPLEXES
Other Titles
THE SYNTHESIS OF ACETIC-ACID FROM METHYL FORMATE CATALYZED BY NICKEL-COMPLEXES
Author
CHEONG, MinsekLEE, Si H.SA, Young S.Lee, Jae SungKIM, Young G.
Keywords
COORDINATED CARBON-MONOXIDE; GAS SHIFT REACTION; METHANOL CARBONYLATION; HOMOGENEOUS CATALYSIS; RHODIUM; ISOMERIZATION; ALKYL; ACTIVATION; MIGRATION; SYSTEM
Issue Date
1991-09
Publisher
Elsevier BV
Citation
JOURNAL OF MOLECULAR CATALYSIS, v.68, no.3, pp.277 - 288
Abstract
A highly efficient catalyst system consisting of a nickel complex, a trialkylamine, and a tetraaklyltin was studied for the isomerization of methyl formate to acetic acid. The effects of temperature, solvent, methyl formate concentration and CO partial pressure on the rate and selectivity of the reaction were investigated. The role of promoter tetraalkyltin as a Lewis acid and synergistic effects between promoters are explained using a proposed mechanism
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DOI
10.1016/0304-5102(91)80086-I
ISSN
0304-5102
Appears in Collections:
ECHE_Journal Papers
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