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곽자훈

Kwak, Ja Hun
Molecular Catalysis Lab.
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XE-129 NMR-SPECTRUM OF XENON IN THE ALPHA-CAGE OF ZEOLITE A DURING HYDRATION AND ION-EXCHANGE

Alternative Title
XE-129 NMR-SPECTRUM OF XENON IN THE ALPHA-CAGE OF ZEOLITE A DURING HYDRATION AND ION-EXCHANGE
Author(s)
RYOO, RDEMENORVAL, LCKwak, JahunFIGUERAS, F
Issued Date
1993-04
DOI
10.1021/j100118a032
URI
https://scholarworks.unist.ac.kr/handle/201301/12480
Fulltext
http://pubs.acs.org/doi/abs/10.1021/j100118a032
Citation
JOURNAL OF PHYSICAL CHEMISTRY, v.97, no.16, pp.4124 - 4127
Abstract
Xenon was forced into the alpha-cage of dehydrated NaA zeolite by heating to 523 K, with sufficiently high pressure of xenon (e.g., 14 atm) to increase the xenon concentration. After the sample was cooled to room temperature, the xenon was isolated as occluded in the zeolite cage. The Xe-129 NMR spectra for such occluded xenon showed remarkable changes in the line shape and the chemical shift during hydration and ion exchange of the zeolite, serving as an in-situ internal probe
Publisher
American Chemical Society
ISSN
0022-3654

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