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곽자훈

Kwak, Ja Hun
Molecular Catalysis Lab.
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Direct observation of ion exchange in mechanically activated LiH+MgB2 system using ultrahigh field nuclear magnetic resonance spectroscopy

Alternative Title
Direct observation of ion exchange in mechanically activated LiH+MgB2 system using ultrahigh field nuclear magnetic resonance spectroscopy
Author(s)
Hu, Jian ZhiKwak, JahunYang, ZhenguoWan, XuefeiShaw, Leon L.
Issued Date
2009-04
DOI
10.1063/1.3110966
URI
https://scholarworks.unist.ac.kr/handle/201301/12337
Fulltext
http://scitation.aip.org/content/aip/journal/apl/94/14/10.1063/1.3110966
Citation
APPLIED PHYSICS LETTERS, v.94, no.14, pp.141905
Abstract
The LiBH4+MgH2 system has great potential for hydrogen vehicle applications. In this study, the reported solid-state hydrogenation system made of LiH+1/2MgB(2) has been investigated using ultrahigh field nuclear magnetic resonance spectroscopy. It is found that Mg-Li ion exchange occurs within MgB2 during ball milling to form a compound of (Mg1-xLi2x)B-2, which facilitates the formation of LiBH4 in the subsequent hydriding reaction. This discovery offers a scientific foundation for investigating the detailed mechanisms of solid-state hydrogenation and dehydrogenation of the LiBH4+MgH2 system in the future
Publisher
AMER INST PHYSICS
ISSN
0003-6951
Keyword (Author)
ball millinghydrogen storageion exchangelithium compoundsmagnesium compoundsnuclear magnetic resonance
Keyword
HYDROGEN-STORAGE MATERIALSLITHIUM BOROHYDRIDECOMPLEX HYDRIDESH SYSTEMSLIBH4LIDESTABILIZATIONRELEASECARBONBORON

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