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Ryu, Ja-Hyoung
Supramolecular NanoMaterials Lab (SUN)
Research Interests
  • Supramolecular assembly, synthetic peptide assembly, cancer drug delivery

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Helical organization of m-linked rigid polymers with pendant flexible dendrons

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Title
Helical organization of m-linked rigid polymers with pendant flexible dendrons
Other Titles
Helical organization of m-linked rigid polymers with pendant flexible dendrons
Author
Ja-Hyoung RyuJinyoung BaeMyongsoo Lee
Keywords
NONBIOLOGICAL OLIGOMERS; SECONDARY STRUCTURE; CARBON NANOTUBES; FOLDAMERS; PACKING
Issue Date
2005-03
Publisher
AMER CHEMICAL SOC
Citation
MACROMOLECULES, v.38, no.6, pp.2050 - 2052
Abstract
The synthesis of conformationally flexible, m-linked rigid monomers containing flexible side group and its polymerization with 4,4′- bis(bromomethyl)biphenyl to yield m-linked aromatic polymers were discussed. The secondary structure of the resulting polymers appeared to be dependent on the molecular structure of the side group in the solid state. The polymer based on a bulky dendritic chain adopted a helical conformation that self-organized into a tetragonal columnar structure. Analysis suggests that this class of self-assembling system may allow the design of well-defined helical tubules with desired functions.
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DOI
10.1021/ma0473723
ISSN
0024-9297
Appears in Collections:
PHY_Journal Papers
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