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Bielawski, Christopher W.
Synthetic Materials & Macromolecules
Research Interests
  • Synthetic chemistry, materials science, polymer chemistry, catalysis, carbon-based materials

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Assessing the reactivity of the N,N '-diamidocarbenes toward compounds containing early p-block elements

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Title
Assessing the reactivity of the N,N '-diamidocarbenes toward compounds containing early p-block elements
Author
Lastovickova, Dominika N.Moerdyk, Jonathan P.Kelley, Andrea R.Bielawski, Christopher W.
Issue Date
2015-02
Publisher
WILEY-BLACKWELL
Citation
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, v.28, no.2, pp.75 - 78
Abstract
The ability of an isolable N,N-diamidocarbene (DAC) to activate compounds containing early p-block elements was explored. At ambient temperature, the DAC formally inserted into the Si-H bonds of various silanes to afford the corresponding DAC-silane adducts. The aforementioned adducts did not undergo intramolecular ring expansion as observed with other carbene-silane analogues. The DAC was also found to form a coordination complex with aluminum chloride, and a structurally rich, tris(aluminum) species was obtained upon exposure of the DAC to trimethylaluminum. The results gleaned from these studies are expected to facilitate the development of novel organometallic species as well as of new types of organocatalyzed silylations and aluminations. Copyright (c) 2014 John Wiley & Sons, Ltd
URI
https://scholarworks.unist.ac.kr/handle/201301/10905
URL
http://onlinelibrary.wiley.com/doi/10.1002/poc.3388/abstract;jsessionid=36E138F43531AA7F31F06764B9D61811.f01t01
DOI
10.1002/poc.3388
ISSN
0894-3230
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PHY_Journal Papers
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