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Jung, Yoon Seok
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Conformal Surface Coatings to Enable High Volume Expansion Li-Ion Anode Materials

Author(s)
Riley, Leah A.Cavanagh, Andrew S.George, Steven M.Jung, Yoon SeokYan, YanfaLee, Se-HeeDillon, Anne C.
Issued Date
2010-07
DOI
10.1002/cphc.201000158
URI
https://scholarworks.unist.ac.kr/handle/201301/10020
Fulltext
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=77954800026
Citation
CHEMPHYSCHEM, v.11, no.10, pp.2124 - 2130
Abstract
An alumina surface coating is demonstrated to improve electrochemical performance of MoO(3) nanoparticles as high capacity/high-volume expansion anodes for Li-ion batteries. Thin, conformal surface coatings were grown using atomic layer; deposition (ALD) that relies on self-limiting surface reactions. ALD coatings were tested on both individual nanoparticles and prefabricated electrodes containing conductive additive and binder. The coated and non-coated materials were characterized using transmission electron microscopy, energy-dispersive; X-ray spectroscopy, electrochemical impedance spectroscopy, and galvanostatic charge/discharge cycling. Importantly, increased stability and capacity retention was only observed when the fully fabricated electrode was coated. The alumina layer both improves the adhesion of the entire electrode, during volume expansion/contraction and protects the nanoparticle surfaces. Coating the entire electrode also allows for an important carbothermal reduction process that occurs during electrode pre-heat treatment. ALD is thus demonstrated as a novel and necessary method that may be employed to coat the tortuous network of a battery electrode.
Publisher
WILEY-V C H VERLAG GMBH
ISSN
1439-4235

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