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Jung, Yoon Seok
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Extremely Durable High-Rate Capability of a LiNi0.4Mn0.4Co0.2O2 Cathode Enabled with Single-Walled Carbon Nanotubes

Author(s)
Ban, ChunmeiLi, ZhengWu, ZhuangchunKirkham, Melanie J.Chen, LeJung, Yoon SeokPayzant, E. AndrewYan, YanfaWhittingham, M. StanleyDillon, Anne C.
Issued Date
2011-01
DOI
10.1002/aenm.201000001
URI
https://scholarworks.unist.ac.kr/handle/201301/10014
Fulltext
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=80051794213
Citation
ADVANCED ENERGY MATERIALS, v.1, no.1, pp.58 - 62
Abstract
A binder-free LiNi0.4Mn0.4Co0.2O2 cathode fabricated with 5 wt.% single-walled carbon nanotubes (SWNTS) shows excellent cycling performance at rates of 10C (Charge/discharge in 6 minutes). In contrast, a LiNi0.4Mn0.4Co0.2O2 electrode prepared by conventional methods without SWNTs has a significantly lower capacity. Based on the morphology and structural analysis, this exceptional rate capability is due to highly intimate contact between the long crystalline SWNT ropes and the active cathode material, ensuring fast diffusion of ions and electrons during cycling and resulting in sustainable capacity at high rates for 500 cycles.
Publisher
WILEY-V C H VERLAG GMBH
ISSN
1614-6832

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