BROWSE

Related Researcher

Author

Schultz, Thomas
CRASY(Correlated Rotational Alignment Spectroscopy)
Research Interests
  • Correlated spectroscopy

ITEM VIEW & DOWNLOAD

Two-photon photoelectron spectrum of methyl iodide through a dissociative intermediate state

Cited 11 times inthomson ciCited 10 times inthomson ci
Title
Two-photon photoelectron spectrum of methyl iodide through a dissociative intermediate state
Author
Schultz, ThomasFischer, I
Keywords
PHOTODISSOCIATION DYNAMICS; MULTIPHOTON IONIZATION; 2-PHOTON IONIZATION; ENERGY; CH3I; SPECTROSCOPY; MOLECULES; ENHANCEMENT; LIFETIMES
Issue Date
199710
Publisher
AMER CHEMICAL SOC
Citation
JOURNAL OF PHYSICAL CHEMISTRY A, v.101, no.28, pp.5031 - 5034
Abstract
The two-photon photoelectron spectrum of methyl iodide was recorded in a magnetic bottle time-of-flight spectrometer. As absorption of the first photon is resonant with the dissociative A-state continuum of methyl iodide, the experiment corresponds to a bound-free-bound transition. A progression in the C-I stretching vibration is observed, which corresponds, in a simplified picture, to the dissociation coordinate. The results agree well with recently published two-photon ZEKE spectra of CH3I. This similarity has impact on an ongoing discussion about discrepancies between calculated and measured intensities in two-photon ionization spectra.
URI
Go to Link
DOI
http://dx.doi.org/10.1021/jp971001p
ISSN
1089-5639
Appears in Collections:
SNS_Journal Papers

find_unist can give you direct access to the published full text of this article. (UNISTARs only)

Show full item record

qr_code

  • mendeley

    citeulike

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

MENU