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Schultz, Thomas
CRASY(Correlated Rotational Alignment Spectroscopy)
Research Interests
  • Correlated spectroscopy

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The nonradiative decay of the allyl radical excited B 2A1 state studied by picosecond time-resolved photoelectron spectroscopy

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Title
The nonradiative decay of the allyl radical excited B 2A1 state studied by picosecond time-resolved photoelectron spectroscopy
Author
Schultz, ThomasFischer, I
Keywords
RESONANT MULTIPHOTON IONIZATION; ULTRAFAST INTERNAL-CONVERSION; KINETIC-ENERGY PHOTOELECTRON; ELECTRONIC-SPECTRUM; RYDBERG STATES; SUPERSONIC JET; ORIGIN BAND; DYNAMICS; PHOTOIONIZATION; RELAXATION
Issue Date
199712
Publisher
AMER INST PHYSICS
Citation
JOURNAL OF CHEMICAL PHYSICS, v.107, no.19, pp.8197 - 8200
Abstract
The nonradiative decay rates of the vibrational ground state and the v7 fundamental in the electronically excited B 2A1 state of the allyl radical, C3H5, are studied by picosecond time-resolved pump-probe photoelectron spectroscopy. The states decay by internal conversion with a time constant of 20 and 16 ps, respectively.
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DOI
http://dx.doi.org/10.1063/1.475121
ISSN
0021-9606
Appears in Collections:
SNS_Journal Papers
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