Untangling pi-pi*/n-pi* orbital interactions via time-resolved photoelectron spectroscopy
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- Untangling pi-pi*/n-pi* orbital interactions via time-resolved photoelectron spectroscopy
- Shaffer, JP; Schultz, Thomas; Schmitt, M; Underwood, JG; Stolow, A
- Issue Date
- Springer Verlag
- SPRINGER SERIES IN CHEMICAL PHYSICS, v.66, no., pp.338 - 340
- The ultrafast photochemical dynamics of π-π*/n-π* orbital interactions are determined using time-resolved photoelectron spectroscopy. We compare the spectra of several linear α,β-enones and 1,3-butadiene. We find two different ultrafast decay paths for the α,β-enones, both predicted by ab initio calculations.
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