BROWSE

Related Researcher

Author

Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)

ITEM VIEW & DOWNLOAD

Novel 36-membered dodecanuclear manganese metalladiazamacrocycle

Cited 50 times inthomson ciCited 48 times inthomson ci
Title
Novel 36-membered dodecanuclear manganese metalladiazamacrocycle
Author
John, RPLee, KLah, Myoung Soo
Keywords
METALLAMACROCYCLES; COMPLEXES; FRAMEWORK; LIGANDS; SERIES
Issue Date
2004
Publisher
ROYAL SOC CHEMISTRY
Citation
CHEMICAL COMMUNICATIONS, v., no.23, pp.2660 - 2661
Abstract
A novel dodecanuclear manganese metalladiazamacrocycle was synthesized employing a new pentadentate ligand N-2-pentenoylsalicylhydrazide (H 3tpeshz) by supramolecular self-assembly. The backbone of this metal-organic assembly is a repeating unit of an M-N-N-M linkage that extends to complete a 36-membered cyclic structure involving 12 manganese(III) centers. Successive manganese centers are in a chemically different ⋯ ABABAB⋯-type environment while the chirality varies as ⋯ΛΛΔΔΛΛ⋯. The unique arrangement of manganese centers results in a highly puckered metalladiazamacrocycle with an S6-point group symmetry.
URI
Go to Link
DOI
http://dx.doi.org/10.1039/b407668k
ISSN
1359-7345
Appears in Collections:
SNS_Journal Papers

find_unist can give you direct access to the published full text of this article. (UNISTARs only)

Show full item record

qr_code

  • mendeley

    citeulike

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

MENU