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Lah, Myoung Soo
Frontier Energy Storage Material Lab.
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Steric control of the nuclearity of metallamacrocycles: formation of a hexanuclear gallium metalladiazamacrocycle and a hexadecanuclear manganese metalladiazamacrocycle

Author(s)
Lee, KyungjinJohn, Rohith P.Park, MiraMoon, DohyunRi, Hyeong-CheolKim, Ghyung HwaLah, Myoung Soo
Issued Date
2008
DOI
10.1039/b711686a
URI
https://scholarworks.unist.ac.kr/handle/201301/5809
Fulltext
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=37249078279
Citation
DALTON TRANSACTIONS, no.1, pp.131 - 136
Abstract
An S-6-symmetric hexanuclear gallium metalladiazamacrocycle, [Ga-III (6L6S6)-S-2] with a-(Lambda Delta)(Lambda Delta)-chiral sequence and an S-8-symmetric hexadecanuclear manganese metalladiazamacrocycle, [Mn-III (16L16S16)-S-2] with a-(Lambda Lambda Delta Delta)(Lambda Lambda Delta Delta)-chiral sequence were prepared using the same N-2-trans-cinnamoyl-2-hydroxy-3- naphthoylhydrazide (H3L2) as a bridging pentadentate ligand between the metal centers for the formation of a macrocyclic system.
Publisher
ROYAL SOC CHEMISTRY
ISSN
1477-9226
Keyword
COMPLEXESCOORDINATIONFRAMEWORKMOLECULEWHEELSIZERECOGNITIONNETWORKSSYMMETRYLIGANDS

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