Electrochemical properties of B-site Ni doped layered perovskite cathodes for IT-SOFCs
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- Electrochemical properties of B-site Ni doped layered perovskite cathodes for IT-SOFCs
- Jun, Areum; Lim, Tak-hyoung; Shin, Jeeyoung; Kim, Guntae
- Cathode; Electrochemical performance; Layered perovskite; Solid oxide fuel cells (SOFCs)
- Issue Date
- PERGAMON-ELSEVIER SCIENCE LTD
- INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, v.39, no.35, pp.20791 - 20798
- Offering fast oxygen reduction kinetics and high electrical conductivities relative to those of ABO3-type perovskite oxides, layered perovskite cathode materials have received considerable attention for intermediate temperature solid oxide fuel cells (IT-SOFCs). In this study, we have investigated the effects of Ni substitution for the Co site in SmBa0.5Sr0.5Co2O5+δ in terms of structural characteristics, electrical properties, and electrochemical performance of SmBa0.5Sr0.5Co2-xNixO5+δ (x=0, 0.1, and 0.2) in relation to its application as an IT-SOFC cathode material. At the given temperature, the electrical conductivities of SmBa0.5Sr0.5Co2-xNixO5+δ (x=0, 0.1, and 0.2) decrease with increasing Ni content. For x=0.1, the lowest ASR value, 0.125Ωcm2, and the highest single cell performance, 1.78Wcm-2 at 600°C, are obtained.
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