A layer-built rechargeable lithium ribbon-type battery for high energy density textile battery applications
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- A layer-built rechargeable lithium ribbon-type battery for high energy density textile battery applications
- Kim, Jae-Kwang; Scheers, Johan; Ryu, Ho-Suk; Ahn, Jou-Hyeon; Nam, Tae-Hyun; Kim, Ki-Won; Ahn, Hyo-Jun; Cho, Gyu-Bong; Jacobsson, Per
- LI-ION BATTERIES; LIFEPO4 CATHODE MATERIAL; ORGANIC RADICAL BATTERY; ELECTROCHEMICAL PERFORMANCE; STORAGE MATERIALS; IRON PHOSPHATE; POLYMER; ELECTRODE; COMPOSITES; ANODES
- Issue Date
- ROYAL SOC CHEMISTRYROYAL SOC CHEMISTRY
- JOURNAL OF MATERIALS CHEMISTRY A, v.2, no.6, pp.1774 - 1780
- We designed a novel layer-built rechargeable lithium ribbon-type battery intended for textile or cloth based applications. The ribbon-type battery, 2.4 mm (or 1 mm) wide and 10 cm long, is composed of a double layer LiFePO4 cathode and an amorphous silicon nanofilm. The double layer LiFePO4 and amorphous silicon electrodes were prepared using the doctor blade method and a vertical deposition technique, respectively. The structure and morphology of the LiFePO4 and the silicon thin film were characterized by Rietveld refinement, SEM and TEM. At room temperature the ribbon-type battery exhibited an initial discharge capacity of 166.4 and 132.7 mA h g (1) at 0.5 and 1 C-rate, respectively. A reasonably good cycling performance and high coulombic efficiency under the high current density of 1 C-rate could be obtained with the Si/LiFePO4 ribbon-type battery. Also, a high volumetric capacity of 336 mA h cm (3) at 0.5 C-rate was achieved, which makes the ribbon-type battery suitable for practical use.
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