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Author

Bielawski, Christopher W.
Synthetic Materials & Macromolecules
Research Interests
  • Synthetic chemistry, materials science, polymer chemistry, catalysis, carbon-based materials

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Dynamic 2D manganese(ii) isonicotinate framework with reversible crystal-to-amorphous transformation and selective guest adsorption

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Title
Dynamic 2D manganese(ii) isonicotinate framework with reversible crystal-to-amorphous transformation and selective guest adsorption
Author
Matoga, DariuszGil, BarbaraNitek, WojciechTodd, Alexander D.Bielawski, Christopher W.
Keywords
METAL-ORGANIC FRAMEWORKS; HYDROGEN STORAGE PROPERTIES; MN2+ COORDINATION SITES; MAGNETIC-PROPERTIES; GAS-ADSORPTION; CO2 CAPTURE; SEPARATION; STABILITY; ALCOHOLS; CHANNELS
Issue Date
201406
Publisher
ROYAL SOC CHEMISTRY
Citation
CRYSTENGCOMM, v.16, no.23, pp.4959 - 4962
Abstract
A 2D layered microporous isonicotinate-supported manganese(ii) metal-organic framework was found to exhibit a reversible crystal-to-amorphous transformation upon the removal and uptake of certain guest molecules. Unsaturated metal centers, generated in the dynamic framework upon activation, were found to facilitate the selective adsorption of CO2versus N 2.
URI
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DOI
http://dx.doi.org/10.1039/c4ce00647j
ISSN
1466-8033
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