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- Cho, Jaeheung
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A bis(mu-alkylperoxo)dinickel(II) complex as a reaction intermediate for the oxidation of the methyl groups of the Me-2-tpa ligand to carboxylate and alkoxide ligands
- Author(s)
- Cho, Jaeheung, Furutachi, Hideki, Fujinami, Shuhei, Suzuki, Masatatsu
- Issued Date
- 2004-06
- Citation
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.43, no.25, pp.3300 - 3303
- Abstract
- A radical approach: The reaction of [Ni2(OH)2(Me2‐tpa)2]2+ with H2O2 resulted in the peroxidation of a methyl group of the Me2‐tpa ligand to produce a bis(μ‐alkylperoxo)dinickel(II) complex (see ORTEP diagram) as a reaction intermediate for further oxidation to carboxylato and alkoxo complexes [Ni(Me1‐tpa‐COO)]+ and [Ni2(Me1‐tpa‐CH2O)2]2+. Me2‐tpa=bis[(6‐methyl‐2‐pyridyl)methyl][(2‐pyridyl)methyl]amine.
- Publisher
- Wiley
- ISSN
- 1433-7851
- Keyword (Author)
- nickel, oxidation, peroxides, reaction mechanisms
- Keyword
- ALKYLPEROXO COMPLEX, NONHEME, OXYGENATION, CONVERSION, ALKYL
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