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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 3303 | - |
dc.citation.number | 25 | - |
dc.citation.startPage | 3300 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 43 | - |
dc.contributor.author | Cho, Jaeheung | - |
dc.contributor.author | Furutachi, Hideki | - |
dc.contributor.author | Fujinami, Shuhei | - |
dc.contributor.author | Suzuki, Masatatsu | - |
dc.date.accessioned | 2023-12-22T11:06:04Z | - |
dc.date.available | 2023-12-22T11:06:04Z | - |
dc.date.created | 2020-09-01 | - |
dc.date.issued | 2004-06 | - |
dc.description.abstract | A radical approach: The reaction of [Ni2(OH)2(Me2‐tpa)2]2+ with H2O2 resulted in the peroxidation of a methyl group of the Me2‐tpa ligand to produce a bis(μ‐alkylperoxo)dinickel(II) complex (see ORTEP diagram) as a reaction intermediate for further oxidation to carboxylato and alkoxo complexes [Ni(Me1‐tpa‐COO)]+ and [Ni2(Me1‐tpa‐CH2O)2]2+. Me2‐tpa=bis[(6‐methyl‐2‐pyridyl)methyl][(2‐pyridyl)methyl]amine. | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.43, no.25, pp.3300 - 3303 | - |
dc.identifier.doi | 10.1002/anie.200353637 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.scopusid | 2-s2.0-4544231478 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/48161 | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/full/10.1002/anie.200353637 | - |
dc.identifier.wosid | 000222364100015 | - |
dc.language | 영어 | - |
dc.publisher | Wiley | - |
dc.title | A bis(mu-alkylperoxo)dinickel(II) complex as a reaction intermediate for the oxidation of the methyl groups of the Me-2-tpa ligand to carboxylate and alkoxide ligands | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | nickel | - |
dc.subject.keywordAuthor | oxidation | - |
dc.subject.keywordAuthor | peroxides | - |
dc.subject.keywordAuthor | reaction mechanisms | - |
dc.subject.keywordPlus | ALKYLPEROXO COMPLEX | - |
dc.subject.keywordPlus | NONHEME | - |
dc.subject.keywordPlus | OXYGENATION | - |
dc.subject.keywordPlus | CONVERSION | - |
dc.subject.keywordPlus | ALKYL | - |
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