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Cho, Jaeheung
BIOCC at UNIST
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dc.citation.endPage 3303 -
dc.citation.number 25 -
dc.citation.startPage 3300 -
dc.citation.title ANGEWANDTE CHEMIE-INTERNATIONAL EDITION -
dc.citation.volume 43 -
dc.contributor.author Cho, Jaeheung -
dc.contributor.author Furutachi, Hideki -
dc.contributor.author Fujinami, Shuhei -
dc.contributor.author Suzuki, Masatatsu -
dc.date.accessioned 2023-12-22T11:06:04Z -
dc.date.available 2023-12-22T11:06:04Z -
dc.date.created 2020-09-01 -
dc.date.issued 2004-06 -
dc.description.abstract A radical approach: The reaction of [Ni2(OH)2(Me2‐tpa)2]2+ with H2O2 resulted in the peroxidation of a methyl group of the Me2‐tpa ligand to produce a bis(μ‐alkylperoxo)dinickel(II) complex (see ORTEP diagram) as a reaction intermediate for further oxidation to carboxylato and alkoxo complexes [Ni(Me1‐tpa‐COO)]+ and [Ni2(Me1‐tpa‐CH2O)2]2+. Me2‐tpa=bis[(6‐methyl‐2‐pyridyl)methyl][(2‐pyridyl)methyl]amine. -
dc.identifier.bibliographicCitation ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.43, no.25, pp.3300 - 3303 -
dc.identifier.doi 10.1002/anie.200353637 -
dc.identifier.issn 1433-7851 -
dc.identifier.scopusid 2-s2.0-4544231478 -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/48161 -
dc.identifier.url https://onlinelibrary.wiley.com/doi/full/10.1002/anie.200353637 -
dc.identifier.wosid 000222364100015 -
dc.language 영어 -
dc.publisher Wiley -
dc.title A bis(mu-alkylperoxo)dinickel(II) complex as a reaction intermediate for the oxidation of the methyl groups of the Me-2-tpa ligand to carboxylate and alkoxide ligands -
dc.type Article -
dc.description.isOpenAccess FALSE -
dc.type.docType Article -
dc.description.journalRegisteredClass scie -
dc.description.journalRegisteredClass scopus -
dc.subject.keywordAuthor nickel -
dc.subject.keywordAuthor oxidation -
dc.subject.keywordAuthor peroxides -
dc.subject.keywordAuthor reaction mechanisms -
dc.subject.keywordPlus ALKYLPEROXO COMPLEX -
dc.subject.keywordPlus NONHEME -
dc.subject.keywordPlus OXYGENATION -
dc.subject.keywordPlus CONVERSION -
dc.subject.keywordPlus ALKYL -

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