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Kwak, Ja Hun
Molecular Catalysis lab
Research Interests
  • Heterogeneous catalysis, molecular catalysis, ASlumima, zeolites

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A common intermediate for N2 formation in enzymes and zeolites: Side-On Cu-nitrosyl complexes

Cited 10 times inthomson ciCited 4 times inthomson ci
Title
A common intermediate for N2 formation in enzymes and zeolites: Side-On Cu-nitrosyl complexes
Author
Kwak, JahunLee, Jong H.Burton, Sarah D.Lipton, Andrew S.Peden, Charles H. F.Szanyi, Janos
Keywords
IR spectroscopy; NMR spectroscopy; reaction mechanisms; reduction; zeolites
Issue Date
201309
Publisher
WILEY-V C H VERLAG GMBH
Citation
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.52, no.38, pp.9985 - 9989
Abstract
Side on Combined FTIR and NMR studies revealed the presence of a side-on nitrosyl species in the zeolite Cu-SSZ-13. This intermediate is very similar to those found in nitrite reductase enzyme systems. The identification of this intermediate led to the proposal of a reaction mechanism that is fully consistent with the results of both kinetic and spectroscopic studies.
URI
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DOI
http://dx.doi.org/10.1002/anie.201303498
ISSN
1433-7851
Appears in Collections:
ECHE_Journal Papers

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