A common intermediate for N2 formation in enzymes and zeolites: Side-On Cu-nitrosyl complexes
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- A common intermediate for N2 formation in enzymes and zeolites: Side-On Cu-nitrosyl complexes
- Kwak, Jahun; Lee, Jong H.; Burton, Sarah D.; Lipton, Andrew S.; Peden, Charles H. F.; Szanyi, Janos
- IR spectroscopy; NMR spectroscopy; reaction mechanisms; reduction; zeolites
- Issue Date
- WILEY-V C H VERLAG GMBH
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.52, no.38, pp.9985 - 9989
- Side on Combined FTIR and NMR studies revealed the presence of a side-on nitrosyl species in the zeolite Cu-SSZ-13. This intermediate is very similar to those found in nitrite reductase enzyme systems. The identification of this intermediate led to the proposal of a reaction mechanism that is fully consistent with the results of both kinetic and spectroscopic studies.
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