Electrochemical performance of YST infiltrated and fe doped YST infiltrated YSZ anodes for IT-SOFC
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- Electrochemical performance of YST infiltrated and fe doped YST infiltrated YSZ anodes for IT-SOFC
- Sengodan, Sivaprakash; Yoon, Jong Seol; Yoon, Mi Young; Hwang, Hae Jin; Shin, Jeeyoung; Kim, Guntae
- OXIDE FUEL-CELLS; ELECTRICAL-CONDUCTIVITY; PEROVSKITES; OXIDATION; METHANE; CATHODES; SRTIO3; CO
- Issue Date
- The Electrochemical Society
- ECS ELECTROCHEMISTRY LETTERS, v.2, no.6, pp.F45 - F49
- Donor doped and donor-acceptor co-doped strontium titanate perovskite are investigated for intermediate temperature solid oxide fuel cells (IT-SOFCs) anodes. Y0.08Sr0.88TiO3-delta and Y0.08Sr0.92Ti1-xFexO3-delta (x = 0.2, 0.4) anodes were prepared by infiltration in 65% porous yttria stabilized zirconia (YSZ) scaffolds. The microstructure and electrical conductivity of Y0.08Sr0.88TiO3-delta and Y0.08Sr0.92Ti1-xFexO3-delta strongly depends on Fe content. The conductivity of Y0.08Sr0.88TiO3-delta andY(0.08)Sr(0.92)Ti(1-x)Fe(x)O(3-delta); decreases with increasing Fe content in humidified H-2. Y0.08Sr0.88TiO3-delta, Y0.08Sr0.92Ti0.8Fe0.2O3-delta, and Y0.08Sr0.92Ti0.6Fe0.4O3-delta, anodes with a Pd/CeO2 catalyst show peak power density of 298, 421, and 321 mW cm(-2), respectively, in wet H-2 at 1073 K.
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