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Kim, Kwang S.
Center for Superfunctional Materials (CSM)
Research Interests
  • Theoretical/experimental nanosciences, molecular electronics spectroscopy, energy materials

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Turn-on and Turn-off Fluorescent Probes for Carbon Monoxide Detection and Blood Carboxyhemoglobin Determination

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Title
Turn-on and Turn-off Fluorescent Probes for Carbon Monoxide Detection and Blood Carboxyhemoglobin Determination
Author
Shi, GenggongwoYoon, TaeseungCha, SeoncheolKim, SeulgiYousuf, MuhammadAhmed, NisarKim, DoseokKang, Hyun-WookKim, Kwang S.
Keywords
azidocarbonylation; blood carboxyhemoglobin; carbon monoxide; fluorescent probe; gas sensing
Issue Date
201806
Publisher
AMER CHEMICAL SOC
Citation
ACS SENSORS, v.3, no.6, pp.1102 - 1108
Abstract
Water-soluble, carbazole-based two-photon excitable fluorescent probes MPVC-I ("turn-on") and MPVC-II ("turn-off") are rationally designed and synthesized for the selective monitoring of carbon monoxide (CO). Both probes can effectively measure carboxyhemoglobin (HbCO) in the blood of the animals exposed to a CO dose as low as 100 ppm for 10 min. The palladium catalyzed azidocarbonylation reaction was optimized to improve the sensing efficiency.
URI
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DOI
http://dx.doi.org/10.1021/acssensors.8b00083
ISSN
2379-3694
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