JOURNAL OF CHEMICAL PHYSICS, v.128, no.15, pp.845 - 850
Abstract
Indium was substituted at gallium site in chalcopyrite AgGaS(2) structure by using a simple solid solution method. The spectroscopic analysis using extended x-ray absorption fine structure and x-ray photoelectron spectroscopy confirmed the indium substitution in AgGaS(2) lattice. The band gap energy of AgGa(1-x)In(x)S(2) (x=0 - 1) estimated from the onset of absorption edge was found to be reduced from 2.67 eV (x=0 ) to 1.9 eV (x=1 ) by indium substitution. The theoretical and experimental studies showed that the indium s orbitals in AgGa(1-x)In(x)S(2) tailored the band gap energy, thereby modified the photocatalytic activity of the AgGa(1-x)In(x)S(2). (c) 2008 American Institute of Physics