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DC Field | Value | Language |
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dc.citation.endPage | 11463 | - |
dc.citation.number | 24 | - |
dc.citation.startPage | 11461 | - |
dc.citation.title | INORGANIC CHEMISTRY | - |
dc.citation.volume | 47 | - |
dc.contributor.author | Rohde, Jan-Uwe | - |
dc.contributor.author | Kelley, Matthew R. | - |
dc.contributor.author | Lee, Wei-Tsung | - |
dc.date.accessioned | 2023-12-22T08:14:11Z | - |
dc.date.available | 2023-12-22T08:14:11Z | - |
dc.date.created | 2014-12-31 | - |
dc.date.issued | 2008-12 | - |
dc.description.abstract | Mononuclear [Ir{ArNC(NR2)NAr}(C8H12)] complexes (where R = Me or Et; Ar = Ph, 4-MeC6H4, or 2,6-Me2C6H3; and C8H12 = 1,5-cyclooctadiene) were synthesized from the neutral N,N-dialkyl-N′, N″-diarylguanidines via deprotonation and transmetalation. As confirmed by single-crystal structure determinations, the guanidinato(1-) ligands coordinate the low-valent d8 IrI center in an N,N′-chelating binding mode, and the 13C NMR chemical shifts of the alkene carbon atoms establish that these ligands function as stronger donors than related monoanionic, bidentate nitrogen-based ligands. In the reactions of the complexes with O2, the observed reactivity trends correlate with the electronic and steric influences of the substituents of the guanidinato ligands. | - |
dc.identifier.bibliographicCitation | INORGANIC CHEMISTRY, v.47, no.24, pp.11461 - 11463 | - |
dc.identifier.doi | 10.1021/ic801867r | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.scopusid | 2-s2.0-60849089657 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/9765 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=60849089657 | - |
dc.identifier.wosid | 000261510100006 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Synthesis, Characterization, and O2 Reactivity of Iridium(I) Complexes Supported by Guanidinato Ligands | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | RAY CRYSTAL-STRUCTURES | - |
dc.subject.keywordPlus | COORDINATION CHEMISTRY | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | DINUCLEAR | - |
dc.subject.keywordPlus | TITANIUM | - |
dc.subject.keywordPlus | BEHAVIOR | - |
dc.subject.keywordPlus | OLEFIN | - |
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