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DC Field | Value | Language |
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dc.citation.endPage | 3324 | - |
dc.citation.number | 14 | - |
dc.citation.startPage | 3318 | - |
dc.citation.title | CHEMISTRY OF MATERIALS | - |
dc.citation.volume | 23 | - |
dc.contributor.author | Park, Mihyun | - |
dc.contributor.author | Lee, Nohyun | - |
dc.contributor.author | Choi, Seung Hong | - |
dc.contributor.author | An, Kwangjin | - |
dc.contributor.author | Yu, Seung-Ho | - |
dc.contributor.author | Kim, Jeong Hyun | - |
dc.contributor.author | Kwon, Seung-Hae | - |
dc.contributor.author | Kim, Dokyoon | - |
dc.contributor.author | Kim, Hyoungsu | - |
dc.contributor.author | Baek, Sung-Il | - |
dc.contributor.author | Ahn, Tae-Young | - |
dc.contributor.author | Park, Ok Kyu | - |
dc.contributor.author | Son, Jae Sung | - |
dc.contributor.author | Sung, Yung-Eun | - |
dc.contributor.author | Kim, Young-Woon | - |
dc.contributor.author | Wang, Zhongwu | - |
dc.contributor.author | Pinna, Nicola | - |
dc.contributor.author | Hyeon, Taeghwan | - |
dc.date.accessioned | 2023-12-22T06:07:48Z | - |
dc.date.available | 2023-12-22T06:07:48Z | - |
dc.date.created | 2014-12-31 | - |
dc.date.issued | 2011-07 | - |
dc.description.abstract | Lamellar structured ultrathin manganese oxide nanoplates have been synthesized from thermal decomposition of manganese(II) acetylacetonate in the presence of 2,3-dihydroxynaphthalene, which promoted two-dimensional (2-D) growth by acting not only as a strongly binding surfactant but also as a structure-directing agent. Ultrathin manganese oxide nanoplates with a thickness of about 1 rim were assembled into a lamellar structure, and the width of the nanoplates could be controlled from 8 to 70 nm by using various coordinating solvents. X-ray absorption near-edge structure (XANES) spectra at the Mn K edge clearly showed that the nanoplates are mainly composed of Mn(II) species with octahedral symmetry. These hydrophobic manganese oxide nanoplates were ligand-exchanged with amine-terminated poly(ethyleneglycol) to generate water-dispersible nanoplates and applied to T1 contrast agents for magnetic resonance imaging (MRI). They exhibited a very high longitudinal relaxivity (r(1)) value of up to 5.5 mM(-1)s(-1) derived from their high concentration of manganese ions exposed on the surface, and strong contrast enhancement of in vitro and in vivo MR images was observed with a very low dose. | - |
dc.identifier.bibliographicCitation | CHEMISTRY OF MATERIALS, v.23, no.14, pp.3318 - 3324 | - |
dc.identifier.doi | 10.1021/cm200414c | - |
dc.identifier.issn | 0897-4756 | - |
dc.identifier.scopusid | 2-s2.0-79960515455 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/9718 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=79960515455 | - |
dc.identifier.wosid | 000292850700008 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Large-Scale Synthesis of Ultrathin Manganese Oxide Nanoplates and Their Applications to T1 MRI Contrast Agents | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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