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Cho, Jaephil
Nano Energy Storage Materials Lab (NESM)
Research Interests
  • Li-ion battery, metal-air battery, redox-flow battery, flexible battery .

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Scalable Integration of Li5FeO4 towards Robust, High-Performance Lithium-Ion Hybrid Capacitors

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Title
Scalable Integration of Li5FeO4 towards Robust, High-Performance Lithium-Ion Hybrid Capacitors
Author
Park, Min-SikLim, Young-GeunHwang, Soo MinKim, Jung HoKim, Jeom-SooDou, Shi XueCho, JaephilKim, Young-Jun
Issue Date
2014-11
Publisher
WILEY-V C H VERLAG GMBH
Citation
CHEMSUSCHEM, v.7, no.11, pp.3138 - 3144
Abstract
Lithium-ion hybrid capacitors have attracted great interest due to their high specific energy relative to conventional electrical double-layer capacitors. Nevertheless, the safety issue still remains a drawback for lithium-ion capacitors in practical operational environments because of the use of metallic lithium. Herein, single-phase Li5FeO4 with an antifluorite structure that acts as an alternative lithium source (instead of metallic lithium) is employed and its potential use for lithium-ion capacitors is verified. Abundant Li+ amounts can be extracted from Li5FeO4 incorporated in the positive electrode and efficiently doped into the negative electrode during the first electrochemical charging. After the first Li+ extraction, Li+ does not return to the Li5FeO4 host structure and is steadily involved in the electrochemical reactions of the negative electrode during subsequent cycling. Various electrochemical and structural analyses support its superior characteristics for use as a promising lithium source. This versatile approach can yield a sufficient Li+-doping efficiency of >90% and improved safety as a result of the removal of metallic lithium from the cell.
URI
https://scholarworks.unist.ac.kr/handle/201301/9442
URL
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84918506496
DOI
10.1002/cssc.201402397
ISSN
1864-5631
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