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Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)
  • Crystal Engineering
  • Supramolecular coordination chemistry

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Dense CoO/graphene stacks via self-assembly for improved reversibility as high performance anode in lithium ion batteries

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dc.contributor.author Prabakar, S.J. Richard ko
dc.contributor.author Babu, R. Suresh ko
dc.contributor.author Oh, Minhak ko
dc.contributor.author Lah, Myoung Soo ko
dc.contributor.author Han, Su Cheol ko
dc.contributor.author Jeong, Jaehyang ko
dc.contributor.author Pyo, Myoungho ko
dc.date.available 2014-11-21T00:12:49Z -
dc.date.created 2014-11-18 ko
dc.date.issued 2014-12 ko
dc.identifier.citation JOURNAL OF POWER SOURCES, v.272, pp.1037 - 1045 ko
dc.identifier.issn 0378-7753 ko
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/9099 -
dc.description.abstract (Graph Presented) Here, we propose a novel strategy to prepare dense stacks composed of alternating CoO and graphene layers for an anode in lithium ion batteries (LIBs), which contributes to enhanced stability and relatively large reversible capacity. This is accomplished by spontaneously pre-aligning negatively charged CoO-anchored graphene oxide (CG) and positively charged amine-functionalized graphene (GN) in an acidic medium, followed by thermal reduction. The performance of this product is contrasted with that of CG prepared under the identical conditions without the addition of GN, in which CoO nanoparticles are sandwiched between relatively loose and randomly oriented graphene stacks. For example, the composite delivers a capacity greater than 800 mAh g-1 with a fading rate of 0.04 mAh g-1 cycle-1 during 1000 charge/discharge (C/D) cycles at 1.0 A g-1, in contrast to ca. 400 mAh g-1 and 0.24 mAh g-1 cycle-1 for thermally reduced CG without the addition of GN. The origin of the superior electrochemical performance in the dense stacks is ascribed to the enhanced reversibility of a conversion reaction, which in turn contributes to a persistent formation/dissolution of gel-like polymer films (i.e., stable pseudo-capacitance). Experimental evidences that substantiate the aforementioned behaviors (improved reversibility for both processes) are presented. ko
dc.description.statementofresponsibility close -
dc.language 영어 ko
dc.publisher ELSEVIER SCIENCE BV ko
dc.title Dense CoO/graphene stacks via self-assembly for improved reversibility as high performance anode in lithium ion batteries ko
dc.type ARTICLE ko
dc.identifier.scopusid 2-s2.0-84908547908 ko
dc.identifier.wosid 000344208700128 ko
dc.type.rims ART ko
dc.description.wostc 1 *
dc.description.scopustc 0 *
dc.date.tcdate 2015-05-06 *
dc.date.scptcdate 2014-11-18 *
dc.identifier.doi 10.1016/j.jpowsour.2014.09.044 ko
dc.identifier.url http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84908547908 ko
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