BROWSE

Related Researcher

Author's Photo

Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)
  • Crystal Engineering
  • Supramolecular coordination chemistry

ITEM VIEW & DOWNLOAD

Synthesis of mu-oxo and bis(mu-alkoxo) bridged diiron(III) complexes using a tripodal ligand, bis(2-benzimidazolylmethy)ethanolamine with mixed N/O donor atoms

DC Field Value Language
dc.contributor.author Kwak, B ko
dc.contributor.author Lah, Myoung Soo ko
dc.date.available 2014-11-21T00:07:22Z -
dc.date.created 2014-11-19 ko
dc.date.issued 2000-01 ko
dc.identifier.citation BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.21, no.1, pp.65 - 68 ko
dc.identifier.issn 0253-2964 ko
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/9044 -
dc.description.abstract A μ-oxo diiron(III) complex and two bis(μ-alkoxo) diiron(III) complexes with biomimetic tripodal ligand containing mixed N/O donor atoms were synthesized using a mononuclear iron(III) complex as starting material. Depending on the amounts and kinds of bases used, we obtained various kinds of diiron(III) complexes. The reaction of [Fe(III)(Hbbea)Cl2]Cl, 1, with an equivalent amount of KO2 or NaOAc produced [Fe(III)2O(Hbbea)2Cl2]Cl2, 2. An additional equivalent amount of NaOBz or NaOAc converts complex 2 to complex 3 or complex 4 depending on the base used. The addition of two equivalent amounts of NaOBz or NaOAc directly converts complex 1 to [Fe(III)2(bbea)2(OBz)2]Cl2, 3, or [Fe(III)2(bbea)2(OAc)2]Cl2, 4, depending on the base used. Crystal data are as follows: [Fe(III)2O(Hbbea)2Cl2]Cl2, 2: monoclinic space group P21/n, a = 8.421 (1) A, b = 18.416 (2) A, c = 13.736 (1) A, β= 104.870 (7)°, V = 2058.9 (4) A3, Z = 2, R1 = 0.0469 and wR2 = 0.1201 for reflections with I > 2σ(I). ko
dc.description.statementofresponsibility open -
dc.language 영어 ko
dc.publisher KOREAN CHEMICAL SOC ko
dc.title Synthesis of mu-oxo and bis(mu-alkoxo) bridged diiron(III) complexes using a tripodal ligand, bis(2-benzimidazolylmethy)ethanolamine with mixed N/O donor atoms ko
dc.type ARTICLE ko
dc.identifier.scopusid 2-s2.0-0342514804 ko
dc.identifier.wosid 000085055300014 ko
dc.type.rims ART ko
dc.identifier.url http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0342514804 ko
Appears in Collections:
CHM_Journal Papers

find_unist can give you direct access to the published full text of this article. (UNISTARs only)

Show simple item record

qrcode

  • mendeley

    citeulike

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

MENU