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Kwon, Oh Hoon
Ultrafast Laser Spectroscopy and Nano-microscopy (ULSaN Lab)
Research Interests
  • Femtochemistry/biology, 4D electron microscopy, structural dynamics, materials phenomena

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Enhanced solid-state fluorescence in the oxadiazole-based excited-state intramolecular proton-transfer (ESIPT) material: Synthesis, optical property, and crystal structure

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Title
Enhanced solid-state fluorescence in the oxadiazole-based excited-state intramolecular proton-transfer (ESIPT) material: Synthesis, optical property, and crystal structure
Author
Seo, JangwonKim, SehoonLee, Young-ShinKwon, Oh HoonPark, Kang HyunChoi, Soo YoungChung, Young KeunJang, Du-JeonPark, Soo Young
Keywords
Enhanced solid-state fluorescence; Excited-state intramolecular proton-transfer (ESIPT); Oxadiazole; Room-temperature phosphorescence
Issue Date
2007-09
Publisher
ELSEVIER SCIENCE SA
Citation
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, v.191, no.1, pp.51 - 58
Abstract
We report highly fluorescent oxadiazole-based excited-state intramolecular proton-transfer (ESIPT) material, 2,5-bis-[5-(4-tert-butyl-phenyl)-[1,3,4]oxadiazol-2-yl]-phenol (SOX) in solid state film (Φf = 0.47) as well as in solution (Φf = 0.40). From the single crystal X-ray crystallography, a molecular geometry of SOX was found to be nearly planar due to the strong intramolecular hydrogen-bond between the hydroxyl and oxadiazole groups to give rise to the virtually single keto fluorescence. In view of the molecular arrangement, a specific dimer interaction caused by a Coulomb attraction in the SOX crystal was most likely associated with a sliding-away stacking, which contributed to the intense solid-state fluorescence. On the other hand, 2,5-bis-[5-(4-tert-butyl-phenyl)-[1,3,4]oxadiazol-2-yl]-benzene-1,4-diol (DOX) with dual ESIPT sites but otherwise the same as SOX showed a significantly red-shifted orange emission (λem = 573 nm) of keto tautomer relative to the bluish-green emission (λem = 486 nm) of SOX in chloroform. Similarly, the fluorescence emission of DOX in solid-state film (Φf = 0.13) was highly enhanced from that in solution (Φf = 0.02). Interestingly, SOX and DOX showed well-defined room-temperature phosphorescence. Kinetic studies on the ESIPT keto fluorescence as well as the phosphorescence were investigated using picosecond laser experiments.
URI
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DOI
10.1016/j.jphotochem.2007.04.003
ISSN
1010-6030
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PHY_Journal Papers
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