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DC Field | Value | Language |
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dc.citation.endPage | 8631 | - |
dc.citation.number | 28 | - |
dc.citation.startPage | 8624 | - |
dc.citation.title | CHEMISTRY-A EUROPEAN JOURNAL | - |
dc.citation.volume | 14 | - |
dc.contributor.author | Wang, Yishan | - |
dc.contributor.author | Zou, Shan | - |
dc.contributor.author | Kim, Kyoung Taek | - |
dc.contributor.author | Manners, Ian | - |
dc.contributor.author | Winnik, Mitchell A. | - |
dc.date.accessioned | 2023-12-22T08:36:56Z | - |
dc.date.available | 2023-12-22T08:36:56Z | - |
dc.date.created | 2014-11-13 | - |
dc.date.issued | 2008-09 | - |
dc.description.abstract | A new type of metallopolymer-polypeptide block copolymer poly(ferrocenyldimethylsilane)-b-poly (e-benzyloxycarbonyl-L-lysine) was synthesized by ring-opening polymerization of ε-benzyloxycarbonyl-L-lysine N-carboxyanhydride initiated by using a primary amino-terminated poly(ferrocenyldimethylsilane). Studies on the self-organization behavior of this polypeptide block copolymer in both the bulk state and in solution were performed. In the bulk state, a cylindricalin-lamellar structure was observed in a compositionally asymmetric sample. Rod-like micelles with a polyferrocenylsilane core formed in a polypeptideselective solvent alone or in the presence of a common solvent. Significantly, an additional small quantity of the common solvent assisted the formation of longer micelles and micelles with better shape-regularity. This is attributed to a decrease in the number of nucleation events and PFS core reorganization effects. | - |
dc.identifier.bibliographicCitation | CHEMISTRY-A EUROPEAN JOURNAL, v.14, no.28, pp.8624 - 8631 | - |
dc.identifier.doi | 10.1002/chem.200800762 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.scopusid | 2-s2.0-53849085196 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/8746 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=53849085196 | - |
dc.identifier.wosid | 000260035900024 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Organometallic-Polypeptide Block Copolymers: Synthesis and Self-Assembly of Poly(ferrocenyldimethylsilane)-b-Poly(epsilon-benzyloxycarbonyl-L-Lysine) | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | block copolymers | - |
dc.subject.keywordAuthor | micelles | - |
dc.subject.keywordAuthor | polyferrocenylsilane | - |
dc.subject.keywordAuthor | polypeptides | - |
dc.subject.keywordAuthor | rod-coil | - |
dc.subject.keywordPlus | RING-OPENING POLYMERIZATION | - |
dc.subject.keywordPlus | SOLID-STATE STRUCTURE | - |
dc.subject.keywordPlus | DIBLOCK COPOLYMERS | - |
dc.subject.keywordPlus | MICELLAR MORPHOLOGIES | - |
dc.subject.keywordPlus | POLYFERROCENE BLOCK | - |
dc.subject.keywordPlus | SELECTIVE SOLVENT | - |
dc.subject.keywordPlus | CYLINDRICAL MICELLES | - |
dc.subject.keywordPlus | N-CARBOXYANHYDRIDES | - |
dc.subject.keywordPlus | CO-MICELLES | - |
dc.subject.keywordPlus | CRYSTALLINE | - |
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