dc.citation.endPage |
+ |
- |
dc.citation.number |
13 |
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dc.citation.startPage |
3238 |
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dc.citation.title |
INORGANIC CHEMISTRY |
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dc.citation.volume |
38 |
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dc.contributor.author |
Nam, W |
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dc.contributor.author |
Goh, YM |
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dc.contributor.author |
Lee, YJ |
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dc.contributor.author |
Lim, Mi Hee |
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dc.contributor.author |
Kim, C |
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dc.date.accessioned |
2023-12-22T12:11:12Z |
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dc.date.available |
2023-12-22T12:11:12Z |
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dc.date.created |
2014-11-11 |
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dc.date.issued |
1999-06 |
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dc.description.abstract |
n iron(III) porphyrin complex with highly electron-withdrawing substituents on the porphyrin ligand efficiently catalyzes the hydroxylation of alkanes by H2O2 via enzyme mimetic oxidation reactions in aprotic solvent. An "isolated" high-valent iron(IV) oxo porphyrin cation radical intermediate, prepared in situ by reaction of the iron porphyrin complex with m-CPBA at -40 degrees C, is capable of activating C-H bonds of alkanes to give oxygenated products efficiently. The hydroxylating intermediate generated in the catalytic H2O2 reaction is evidenced to be the high-valent iron(IV) oxo porphyrin cation radical species. |
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dc.identifier.bibliographicCitation |
INORGANIC CHEMISTRY, v.38, no.13, pp.3238 - + |
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dc.identifier.doi |
10.1021/ic980670u |
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dc.identifier.issn |
0020-1669 |
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dc.identifier.scopusid |
2-s2.0-0001606867 |
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dc.identifier.uri |
https://scholarworks.unist.ac.kr/handle/201301/8672 |
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dc.identifier.url |
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0001606867 |
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dc.identifier.wosid |
000081189300033 |
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dc.language |
영어 |
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dc.publisher |
AMER CHEMICAL SOC |
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dc.title |
Biomimetic alkane hydroxylations by an iron(III) porphyrin complex with H2O2 and by a high-valent iron(IV) oxo porphyrin cation radical complex |
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dc.type |
Article |
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dc.description.journalRegisteredClass |
scopus |
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