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DC Field | Value | Language |
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dc.citation.endPage | 1039 | - |
dc.citation.number | 5609 | - |
dc.citation.startPage | 1037 | - |
dc.citation.title | SCIENCE | - |
dc.citation.volume | 299 | - |
dc.contributor.author | Rohde, Jan-Uwe | - |
dc.contributor.author | In, JH | - |
dc.contributor.author | Lim, Mi Hee | - |
dc.contributor.author | Brennessel, WW | - |
dc.contributor.author | Bukowski, MR | - |
dc.contributor.author | Stubna, A | - |
dc.contributor.author | Munck, E | - |
dc.contributor.author | Nam, W | - |
dc.contributor.author | Que, L | - |
dc.date.accessioned | 2023-12-22T11:14:07Z | - |
dc.date.available | 2023-12-22T11:14:07Z | - |
dc.date.created | 2014-11-11 | - |
dc.date.issued | 2003-02 | - |
dc.description.abstract | Following the heme paradigm, it is often proposed that dioxygen activation by nonheme monoiron enzymes involves an iron(IV)=oxo intermediate that is responsible for the substrate oxidation step. Such a transient species has now been obtained from a synthetic complex with a nonheme macrocyclic ligand and characterized spectroscopically. Its high-resolution crystal structure reveals an iron-oxygen bond length of 1.646(3) angstroms, demonstrating that a terminal iron(IV)=oxo unit can exist in a nonporphyrin ligand environment and lending credence to proposed mechanisms of nonheme iron catalysis. | - |
dc.identifier.bibliographicCitation | SCIENCE, v.299, no.5609, pp.1037 - 1039 | - |
dc.identifier.doi | 10.1126/science.299.5609.1037 | - |
dc.identifier.issn | 0036-8075 | - |
dc.identifier.scopusid | 2-s2.0-0037436143 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/8662 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0037436143 | - |
dc.identifier.wosid | 000180960000038 | - |
dc.language | 영어 | - |
dc.publisher | AMER ASSOC ADVANCEMENT SCIENCE | - |
dc.title | Crystallographic and spectroscopic characterization of a nonheme Fe(IV)=O complex | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
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