Detailed Information
Cited time in 
Cited time in 
Cited time in
Metadata Downloads
Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.citation.endPage | 6370 | - |
| dc.citation.number | 20 | - |
| dc.citation.startPage | 6366 | - |
| dc.citation.title | INORGANIC CHEMISTRY | - |
| dc.citation.volume | 43 | - |
| dc.contributor.author | Lim, Mi Hee | - |
| dc.contributor.author | Lippard, SJ | - |
| dc.date.accessioned | 2023-12-22T10:42:00Z | - |
| dc.date.available | 2023-12-22T10:42:00Z | - |
| dc.date.created | 2014-11-11 | - |
| dc.date.issued | 2004-10 | - |
| dc.description.abstract | The ruthenium(II) porphyrin fluorophore complexes [Ru(TPP)(CO)(Ds-R)] (TPP = tetraphenylporphinato dianion; Ds = dansyl; R = imidazole (im), 1, or thiomorpholine (tm), 2) were synthesized and investigated for their ability to detect nitric oxide (NO) based on fluorescence. The X-ray crystal structures of 1 and 2 were determined. The Ds-im or Ds-tm ligand coordinates to an axial site of the ruthenium(II) center through a nitrogen or sulfur atom, respectively. Both exhibit quenched fluorescence when excited at 368 or 345 nm. Displacement of the metal-coordinated fluorophore by NO restores fluorescence within minutes. These observations demonstrate fluorescence-based NO detection using ruthenium porphyrin fluorophore conjugates. | - |
| dc.identifier.bibliographicCitation | INORGANIC CHEMISTRY, v.43, no.20, pp.6366 - 6370 | - |
| dc.identifier.doi | 10.1021/ic035418n | - |
| dc.identifier.issn | 0020-1669 | - |
| dc.identifier.scopusid | 2-s2.0-4644241764 | - |
| dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/8658 | - |
| dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=4644241764 | - |
| dc.identifier.wosid | 000224181900036 | - |
| dc.language | 영어 | - |
| dc.publisher | AMER CHEMICAL SOC | - |
| dc.title | Fluorescence-based nitric oxide detection by ruthenium porphyrin fluorophore complexes | - |
| dc.type | Article | - |
| dc.description.journalRegisteredClass | scopus | - |
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.