Detailed Information
Cited time in 
Cited time in 
Cited time in
Metadata Downloads
Copper complexes for fluorescence-based NO detection in aqueous solution
- Author(s)
- Lim, Mi Hee, Lippard, SJ
- Issued Date
- 2005-09
- Citation
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.127, no.35, pp.12170 - 12171
- Abstract
- Two copper(II) complexes containing dansylated ligands were investigated as turn-on fluorescence-based nitric oxide (NO) sensors. Upon addition of NO (g), the quenched fluorescence of both complexes was restored in both organic and buffered aqueous solutions, which is caused by the formation of a diamagnetic Cu(I) species and protonation of the sulfonamide functionality of the ligands. The NO detection limit of these Cu(II) complexes is 10 nM.
- Publisher
- AMER CHEMICAL SOC
- ISSN
- 0002-7863
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.