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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 144 | - |
dc.citation.number | 2 | - |
dc.citation.startPage | 135 | - |
dc.citation.title | EUROPEAN PHYSICAL JOURNAL E | - |
dc.citation.volume | 23 | - |
dc.contributor.author | Kim, Jaeup U. | - |
dc.contributor.author | Matsen, M. W. | - |
dc.date.accessioned | 2023-12-22T09:13:34Z | - |
dc.date.available | 2023-12-22T09:13:34Z | - |
dc.date.created | 2014-11-07 | - |
dc.date.issued | 2007-06 | - |
dc.description.abstract | This paper investigates finite-stretching corrections to the classical Milner-Witten-Cates theory for semi-dilute polymer brushes in a good solvent. The dominant correction to the free energy originates from an entropic repulsion caused by the impenetrability of the grafting surface, which produces a depletion of segments extending a distance μ L -1 from the substrate, where L is the classical brush height. The next most important correction is associated with the translational entropy of the chain ends, which creates the well-known tail where a small population of chains extend beyond the classical brush height by a distance ξ L -1/3. The validity of these corrections is confirmed by quantitative comparison with numerical self-consistent field theory. | - |
dc.identifier.bibliographicCitation | EUROPEAN PHYSICAL JOURNAL E, v.23, no.2, pp.135 - 144 | - |
dc.identifier.doi | 10.1140/epje/i2007-10188-1 | - |
dc.identifier.issn | 1292-8941 | - |
dc.identifier.scopusid | 2-s2.0-34547189616 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/8461 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=34547189616 | - |
dc.identifier.wosid | 000247992300001 | - |
dc.language | 영어 | - |
dc.publisher | SPRINGER | - |
dc.title | Finite-stretching corrections to the Milner-Witten-Cates theory for polymer brushes | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | END-TETHERED POLYMERS | - |
dc.subject.keywordPlus | SELF-CONSISTENT-FIELD | - |
dc.subject.keywordPlus | CLASSICAL-THEORY | - |
dc.subject.keywordPlus | GOOD SOLVENT |
- |
dc.subject.keywordPlus | CHAINS | - |
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