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백종범

Baek, Jong-Beom
Center for Dimension-Controllable Organic Frameworks
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dc.citation.number 1 -
dc.citation.startPage 2407665 -
dc.citation.title SMALL -
dc.citation.volume 21 -
dc.contributor.author Wang, Xu -
dc.contributor.author Zhao, Chong -
dc.contributor.author Yang, Mingyu -
dc.contributor.author Baek, Jae-Hoon -
dc.contributor.author Meng, Zheng -
dc.contributor.author Sun, Bin -
dc.contributor.author Yuan, Aihua -
dc.contributor.author Baek, Jong-Beom -
dc.contributor.author He, Xiao -
dc.contributor.author Jiang, Yi -
dc.contributor.author Zhu, Meifang -
dc.date.accessioned 2024-11-28T16:35:05Z -
dc.date.available 2024-11-28T16:35:05Z -
dc.date.created 2024-11-28 -
dc.date.issued 2025-01 -
dc.description.abstract Herein, a bioinspired metal-organic framework (MOF) cocrystal produced from the co-assembly of a MOF [Ni3(hexaiminobenzene)2, Ni3(HIB)2] and p-chloranils (CHLs) is reported. Because of the 2D conjugation nature and the formation of persistent anion radicals, this cocrystal shows an excellent photothermal property, and is further used as an absorber in solar-driven interfacial water evaporation. The solar-driven interfacial water evaporation rate (4.04 kg m-2 h-1) is among the best compared with those of previously reported photothermal materials. Molecular dynamics simulation results suggested that the rotating of the CHL molecules relative to the MOF planes tuned the pore size to enable the ultra-fast water transporting, and thus ultra-high water transporting rates (1.11 x 1011 and 3.21 x 1011 H2O s-1 channel-1 at 298.2 and 323.0 K, respectively) for layered cocrystal structures, that are much higher than that of aquaporins (approximate to 1.1 x 1010 H2O s-1 channel-1 at 298.2 K), are observed. The superior solar-driven water evaporation performance is thus attributed to the synergistic effect of the ultra-fast water transporting pores together with the excellent photothermal property of the cocrystal. This research provided a biomimetic strategy of rational design and production of charge transfer cocrystals to modulate their pores and photothermal properties for solar-driven interfacial water evaporation. -
dc.identifier.bibliographicCitation SMALL, v.21, no.1, pp.2407665 -
dc.identifier.doi 10.1002/smll.202407665 -
dc.identifier.issn 1613-6810 -
dc.identifier.scopusid 2-s2.0-85207359192 -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/84616 -
dc.identifier.wosid 001344699500001 -
dc.language 영어 -
dc.publisher WILEY-V C H VERLAG GMBH -
dc.title Bioinspired Photothermal Metal-Organic Framework Cocrystal with Ultra-Fast Water Transporting Channels for Solar-Driven Interfacial Water Evaporation -
dc.type Article -
dc.description.isOpenAccess FALSE -
dc.relation.journalWebOfScienceCategory Chemistry, Multidisciplinary; Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter -
dc.relation.journalResearchArea Chemistry; Science & Technology - Other Topics; Materials Science; Physics -
dc.type.docType Article; Early Access -
dc.description.journalRegisteredClass scie -
dc.description.journalRegisteredClass scopus -
dc.subject.keywordAuthor photothermal property -
dc.subject.keywordAuthor solar-driven interfacial water evaporation -
dc.subject.keywordAuthor ultra-fast water transporting channels -
dc.subject.keywordAuthor bioinspired -
dc.subject.keywordAuthor metal-organic framework (MOF) cocrystal -
dc.subject.keywordPlus HIGHLY EFFICIENT -

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