dc.citation.endPage |
3803 |
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dc.citation.number |
24 |
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dc.citation.startPage |
3795 |
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dc.citation.title |
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY |
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dc.contributor.author |
Moon, Hoi Ri |
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dc.contributor.author |
Suh, Myunghyun Paik |
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dc.date.accessioned |
2023-12-22T07:06:25Z |
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dc.date.available |
2023-12-22T07:06:25Z |
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dc.date.created |
2014-11-07 |
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dc.date.issued |
2010-08 |
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dc.description.abstract |
The coordination polymer {[Ni(C(20)H(32)N(8))](2)[TCM]}center dot 5DMF center dot 8H(2)O (1) has been assembled from a Ni(II) macrocyclic complex that contains two pyridyl pendant arms, [Ni(C(20)H(32)N(8))(ClO(4))(2), and sodium tetrakis[4-(carboxyphenyl)oxamethyl]methane (Na(4)TCM) in DMF/water. The X-ray structure of 1 reveals that the pyridyl pendant arms in the macrocyclic complex play a crucial role in determining the network structure through the pi-pi interactions. Compound 1 forms doubly catenated rhombic grids that generate 11) channels. It exhibits flexible behavior upon desorption/resorption and exchange of organic guest molecules as well as temperature change. Solid 1 is redox active due to the incorporated Ni(II) macrocyclic species, and reacts with Pd(NO(3))(2) dissolved in acetonitrile at room temperature to produce small Pd nanoparticles[(2.9 +/- 0.4) nm in diameter] in the channels in the absence of extra reducing or capping agents. |
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dc.identifier.bibliographicCitation |
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, no.24, pp.3795 - 3803 |
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dc.identifier.doi |
10.1002/ejic.201000555 |
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dc.identifier.issn |
1434-1948 |
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dc.identifier.scopusid |
2-s2.0-77955929937 |
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dc.identifier.uri |
https://scholarworks.unist.ac.kr/handle/201301/8428 |
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dc.identifier.url |
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=77955929937 |
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dc.identifier.wosid |
000281684300013 |
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dc.language |
영어 |
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dc.publisher |
WILEY-V C H VERLAG GMBH |
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dc.title |
Flexible and Redox-Active Coordination Polymer: Control of the Network Structure by Pendant Arms of a Macrocyclic Complex |
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dc.type |
Article |
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dc.description.journalRegisteredClass |
scie |
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dc.description.journalRegisteredClass |
scopus |
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