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Moon, Hoi Ri
Functional Inorganic Nanomaterials Lab for Energy
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dc.citation.endPage 3803 -
dc.citation.number 24 -
dc.citation.startPage 3795 -
dc.citation.title EUROPEAN JOURNAL OF INORGANIC CHEMISTRY -
dc.contributor.author Moon, Hoi Ri -
dc.contributor.author Suh, Myunghyun Paik -
dc.date.accessioned 2023-12-22T07:06:25Z -
dc.date.available 2023-12-22T07:06:25Z -
dc.date.created 2014-11-07 -
dc.date.issued 2010-08 -
dc.description.abstract The coordination polymer {[Ni(C(20)H(32)N(8))](2)[TCM]}center dot 5DMF center dot 8H(2)O (1) has been assembled from a Ni(II) macrocyclic complex that contains two pyridyl pendant arms, [Ni(C(20)H(32)N(8))(ClO(4))(2), and sodium tetrakis[4-(carboxyphenyl)oxamethyl]methane (Na(4)TCM) in DMF/water. The X-ray structure of 1 reveals that the pyridyl pendant arms in the macrocyclic complex play a crucial role in determining the network structure through the pi-pi interactions. Compound 1 forms doubly catenated rhombic grids that generate 11) channels. It exhibits flexible behavior upon desorption/resorption and exchange of organic guest molecules as well as temperature change. Solid 1 is redox active due to the incorporated Ni(II) macrocyclic species, and reacts with Pd(NO(3))(2) dissolved in acetonitrile at room temperature to produce small Pd nanoparticles[(2.9 +/- 0.4) nm in diameter] in the channels in the absence of extra reducing or capping agents. -
dc.identifier.bibliographicCitation EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, no.24, pp.3795 - 3803 -
dc.identifier.doi 10.1002/ejic.201000555 -
dc.identifier.issn 1434-1948 -
dc.identifier.scopusid 2-s2.0-77955929937 -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/8428 -
dc.identifier.url http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=77955929937 -
dc.identifier.wosid 000281684300013 -
dc.language 영어 -
dc.publisher WILEY-V C H VERLAG GMBH -
dc.title Flexible and Redox-Active Coordination Polymer: Control of the Network Structure by Pendant Arms of a Macrocyclic Complex -
dc.type Article -
dc.description.journalRegisteredClass scie -
dc.description.journalRegisteredClass scopus -

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