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DC Field | Value | Language |
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dc.citation.startPage | 109874 | - |
dc.citation.title | NANO ENERGY | - |
dc.citation.volume | 128 | - |
dc.contributor.author | Wu, Baoqi | - |
dc.contributor.author | Li, Youle | - |
dc.contributor.author | Liu, Kangzhe | - |
dc.contributor.author | Kim, Seoyoung | - |
dc.contributor.author | Yuan, Xiyue | - |
dc.contributor.author | Pan, Langheng | - |
dc.contributor.author | Zhou, Xia | - |
dc.contributor.author | Tian, Shizeng | - |
dc.contributor.author | Yang, Changduk | - |
dc.contributor.author | Huang, Fei | - |
dc.contributor.author | Cao, Yong | - |
dc.contributor.author | Duan, Chunhui | - |
dc.date.accessioned | 2024-07-26T10:35:12Z | - |
dc.date.available | 2024-07-26T10:35:12Z | - |
dc.date.created | 2024-07-23 | - |
dc.date.issued | 2024-09 | - |
dc.description.abstract | Polymerized small molecular acceptors (PSMAs) have been instrumental in driving the advancements in power conversion efficiencies (PCEs) of all -polymer solar cells (all-PSCs). However, PSMAs commonly face challenges such as low molecular weights and notable batch -to -batch variation, posing significant obstacles to the transition of all-PSCs from lab to fab. Herein, a novel PSMA, which we refer to PAY -IT with an asymmetric conjugated skeleton is reported. The A-D1A'D2-A-type asymmetric monomer endows PAY -IT a random conjugated backbone, thus offering a desired temperature dependent aggregation behavior, which is hardly observed in conventional PSMAs. This characteristic facilitates chain growth during polymerization, thus yielding high molecular weights and low batch -to -batch sensitivity for the polymer. Moreover, the "S -shape" configuration of the asymmetric monomer endows PAY -IT good planarity and excellent charge transport property. As a result, the all-PSC consisted of PAY -IT and PM6 showcased a remarkable PCE of 14.9 %. More importantly, three batches of PAY -IT with number -average molecular weights ranging from 18.3 to 26.2 kDa exhibited nearly identical PCE (14.4-14.9 %), demonstrating superior batch -to -batch reproducibility of this polymer acceptor. This work explored PSMAs with asymmetric skeleton for the first time, and the results demonstrated a new design concept for the development of state-of-the-art PSMAs with minimal batch -to -batch variation. | - |
dc.identifier.bibliographicCitation | NANO ENERGY, v.128, pp.109874 | - |
dc.identifier.doi | 10.1016/j.nanoen.2024.109874 | - |
dc.identifier.issn | 2211-2855 | - |
dc.identifier.scopusid | 2-s2.0-85196179971 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/83305 | - |
dc.identifier.wosid | 001259258500001 | - |
dc.language | 영어 | - |
dc.publisher | ELSEVIER | - |
dc.title | An asymmetric polymerized small molecular acceptor with temperature-dependent aggregation and superior batch-to-batch reproducibility for efficient all-polymer solar cells | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied | - |
dc.relation.journalResearchArea | Chemistry; Science & Technology - Other Topics; Materials Science; Physics | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | All-polymer solar cells | - |
dc.subject.keywordAuthor | Asymmetric structure | - |
dc.subject.keywordAuthor | Polymerized small molecular acceptor | - |
dc.subject.keywordAuthor | Temperature dependent aggregation | - |
dc.subject.keywordAuthor | Reproducibility | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | COPOLYMERS | - |
dc.subject.keywordPlus | INDENOTHIOPHENE | - |
dc.subject.keywordPlus | OPTIMIZATION | - |
dc.subject.keywordPlus | STABILITY | - |
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