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DC Field | Value | Language |
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dc.citation.endPage | 10402 | - |
dc.citation.number | 13 | - |
dc.citation.startPage | 10392 | - |
dc.citation.title | ACS CATALYSIS | - |
dc.citation.volume | 14 | - |
dc.contributor.author | Kim, Hyun-Tak | - |
dc.contributor.author | Park, Jaehyun | - |
dc.contributor.author | Mun, Jinhong | - |
dc.contributor.author | Shin, HyeonOh | - |
dc.contributor.author | Roh, Deok-Ho | - |
dc.contributor.author | Kwon, Junhyeok | - |
dc.contributor.author | Kim, Sungtae | - |
dc.contributor.author | Kim, Sang-Joon | - |
dc.contributor.author | Lee, Geunsik | - |
dc.contributor.author | Kang, Seok Ju | - |
dc.contributor.author | Kwon, Tae-Hyuk | - |
dc.date.accessioned | 2024-07-16T11:05:12Z | - |
dc.date.available | 2024-07-16T11:05:12Z | - |
dc.date.created | 2024-07-16 | - |
dc.date.issued | 2024-07 | - |
dc.description.abstract | Efficient electroreduction of CO2 to multicarbon products is a complicated reaction because of the high energy barriers for the CO2 activation and C-C coupling. Here, we design a graphitic frustrated Lewis pair catalyst doped with boron and nitrogen (BN-GFLP) for reducing the amount of CO2 to multicarbon products. Multicarbon (C2+) biofuels (i.e., ethanol and n-propanol) are identified as the major products with a C(2+ )Faradaic efficiency of 87.9% at a partial current density of -6.0 mA/cm(2) (C2+ Faradaic efficiency of 70.7% at a partial current density of -10.6 mA/cm(2)). Furthermore, density functional theory calculations reveal that the dual binding site of FLP reduces the reaction free energies required for CO2 activation and C-C coupling. Consequently, energetically favorable CO2 reduction pathways are proposed, and selectivities for the production of ethanol and n-propanol are determined. Based on our results, we propose a molecular design strategy for the selective CO2 reduction catalysts aimed at facilitating C(2+ )alcohols production. | - |
dc.identifier.bibliographicCitation | ACS CATALYSIS, v.14, no.13, pp.10392 - 10402 | - |
dc.identifier.doi | 10.1021/acscatal.3c04275 | - |
dc.identifier.issn | 2155-5435 | - |
dc.identifier.scopusid | 2-s2.0-85197509634 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/83177 | - |
dc.identifier.wosid | 001255787900001 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Selective Electroreduction of CO2 to C2+ Alcohols Using Graphitic Frustrated Lewis Pair Catalyst | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | graphitic frustrated Lewis pair | - |
dc.subject.keywordAuthor | electrochemical CO2 reduction | - |
dc.subject.keywordAuthor | electrocatalyst | - |
dc.subject.keywordAuthor | rechargeableCO(2) electrolysis | - |
dc.subject.keywordAuthor | DFT calculations | - |
dc.subject.keywordPlus | REDUCTION | - |
dc.subject.keywordPlus | OXYGEN | - |
dc.subject.keywordPlus | PROBE | - |
dc.subject.keywordPlus | NMR CHEMICAL-SHIFTS | - |
dc.subject.keywordPlus | CARBON-DIOXIDE | - |
dc.subject.keywordPlus | ACID | - |
dc.subject.keywordPlus | SPECTROSCOPY | - |
dc.subject.keywordPlus | EFFICIENCY | - |
dc.subject.keywordPlus | MOLECULE | - |
dc.subject.keywordPlus | METHANOL | - |
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