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DC Field | Value | Language |
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dc.citation.endPage | 521 | - |
dc.citation.number | 5 | - |
dc.citation.startPage | 510 | - |
dc.citation.title | NATURE CATALYSIS | - |
dc.citation.volume | 7 | - |
dc.contributor.author | Tayyebi, Ahmad | - |
dc.contributor.author | Mehrotra, Rashmi | - |
dc.contributor.author | Al Mubarok, Muhibullah | - |
dc.contributor.author | Kim, Jieun | - |
dc.contributor.author | Zafari, Mohammad | - |
dc.contributor.author | Tayebi, Meysam | - |
dc.contributor.author | Oh, Dongrak | - |
dc.contributor.author | Lee, Seong-hun | - |
dc.contributor.author | Matthews, Jesse E. | - |
dc.contributor.author | Lee, Sang-Won | - |
dc.contributor.author | Shin, Tae Joo | - |
dc.contributor.author | Lee, Geunsik | - |
dc.contributor.author | Jaramillo, Thomas F. | - |
dc.contributor.author | Jang, Sung-Yeon | - |
dc.contributor.author | Jang, Ji-Wook | - |
dc.date.accessioned | 2024-05-03T10:35:24Z | - |
dc.date.available | 2024-05-03T10:35:24Z | - |
dc.date.created | 2024-04-18 | - |
dc.date.issued | 2024-05 | - |
dc.description.abstract | Photoelectrochemical production of ammonia (NH3) is potentially eco-friendly but suffers from a low solar-to-ammonia productivity (SAP) and requires a high additional bias for the overall NH3 production from nitrate reduction and water oxidation. Here we applied a high-performance triple-cation lead halide (Cs-0.05(FA(0.83)MA(0.17))(0.95)Pb(Br0.17I0.83)(3)) perovskite photocathode with integrated electrocatalyst to achieve high SAP and coupled glycerol oxidation instead of water oxidation for bias-free NH3 production. Stable, selective NH3 production and glycerol oxidation were achieved by respectively loading Ru and Pt electrocatalysts on conductive and stable titanate nanosheet supports, instead of corrodible carbon-based supports. Our photoelectrochemical NH3 production system coupled to glycerol oxidation demonstrated a photocurrent density of 21.2 +/- 0.7 mA cm(-2) and SAP of 1,744.9 +/- 20.6 mu g(NH3) cm(-)(2) h(-)(1) with 99.5 +/- 0.8% Faradaic efficiency without applying any additional bias. Simultaneously, glycerol was selectively oxidized to glyceric acid as a major value-added product. | - |
dc.identifier.bibliographicCitation | NATURE CATALYSIS, v.7, no.5, pp.510 - 521 | - |
dc.identifier.doi | 10.1038/s41929-024-01133-4 | - |
dc.identifier.issn | 2520-1158 | - |
dc.identifier.scopusid | 2-s2.0-85189092754 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/82289 | - |
dc.identifier.wosid | 001194940900003 | - |
dc.language | 영어 | - |
dc.publisher | NATURE PORTFOLIO | - |
dc.title | Bias-free solar NH3 production by perovskite-based photocathode coupled to valorization of glycerol | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article; Early Access | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | TITANATE | - |
dc.subject.keywordPlus | CELLS | - |
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