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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 1239 | - |
dc.citation.number | 5 | - |
dc.citation.startPage | 1232 | - |
dc.citation.title | ACS ENERGY LETTERS | - |
dc.citation.volume | 2 | - |
dc.contributor.author | Lee, Jinhong | - |
dc.contributor.author | Song, Jongchan | - |
dc.contributor.author | Lee, Hongkyung | - |
dc.contributor.author | Noh, Hyungjun | - |
dc.contributor.author | Kim, Yun-Jung | - |
dc.contributor.author | Kwon, Sung Hyun | - |
dc.contributor.author | Lee, Seung Geol | - |
dc.contributor.author | Kim, Hee-Tak | - |
dc.date.accessioned | 2024-03-26T15:35:09Z | - |
dc.date.available | 2024-03-26T15:35:09Z | - |
dc.date.created | 2024-03-26 | - |
dc.date.issued | 2017-05 | - |
dc.description.abstract | Formation of soluble polysulfide (PS), which is a key feature of lithium sulfur (Li-S) batteries, provides a fast redox kinetic based on a liquid-solid mechanism; however, it imposes the critical problem of PS shuttle. Here, we address the dilemma by exploiting a solvent-swollen polymeric single-ion conductor (SPSIC) as the electrolyte medium of the Li-S battery. The SPSIC consisting of a polymeric single-ion conductor and lithium salt-free organic solvents provides Li ion hopping by forming a nanoscale conducting channel and suppresses PS shuttle according to the Donnan exclusion principle when being employed for Li-S batteries. The organic solvents at the interface of the sulfur/carbon composite and SPSIC eliminate the poor interfacial contact and function as a soluble PS reservoir for maintaining the liquid-solid mechanism. Furthermore, the quasi-solid-state SPSIC allows the fabrication of a bipolar-type stack, which promises the realization of a high-voltage and energy-dense Li-S battery. | - |
dc.identifier.bibliographicCitation | ACS ENERGY LETTERS, v.2, no.5, pp.1232 - 1239 | - |
dc.identifier.doi | 10.1021/acsenergylett.7b00289 | - |
dc.identifier.issn | 2380-8195 | - |
dc.identifier.scopusid | 2-s2.0-85027378075 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/81848 | - |
dc.identifier.wosid | 000401500200042 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | A Nanophase-Separated, Quasi-Solid-State Polymeric Single-Ion Conductor: Polysulfide Exclusion for Lithium-Sulfur Batteries | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical; Electrochemistry; Energy & Fuels; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | LI-S BATTERIES | - |
dc.subject.keywordPlus | ELECTROLYTE | - |
dc.subject.keywordPlus | NAFION | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | INTERLAYER | - |
dc.subject.keywordPlus | SHUTTLE | - |
dc.subject.keywordPlus | CYCLE | - |
dc.subject.keywordPlus | CATHODES | - |
dc.subject.keywordPlus | SYSTEM | - |
dc.subject.keywordPlus | CELLS | - |
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