Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.number | 10 | - |
dc.citation.startPage | 1704 | - |
dc.citation.title | NANOMATERIALS | - |
dc.citation.volume | 12 | - |
dc.contributor.author | Luong, Xuan-Hoang | - |
dc.contributor.author | Pham, Nguyet N. T. | - |
dc.contributor.author | An, Kyoung-Lyong | - |
dc.contributor.author | Lee, Seong Uk | - |
dc.contributor.author | Kim, Shi Surk | - |
dc.contributor.author | Park, Jong S. | - |
dc.contributor.author | Lee, Seung Geol | - |
dc.date.accessioned | 2024-03-19T17:05:11Z | - |
dc.date.available | 2024-03-19T17:05:11Z | - |
dc.date.created | 2024-03-19 | - |
dc.date.issued | 2022-05 | - |
dc.description.abstract | Small metal complexes are highly interesting for bioimaging because of their excellent near-infrared (NIR) absorption properties. In this study, neutral complexes of platinum(II) connected to two monoreduced 1,3-diisopropylimidazoline-2,4,5-trithione ligands-namely, [Pt(iPr(2)timdt)(2)]-were investigated. Theoretical studies using the density functional theory (DFT) and GW-BSE approximation verified the effects of the geometry of the isopropyl moieties on the NIR absorption spectra. The calculated absorption spectra showed excellent correspondence with the experimental results. The geometry of the isopropyl groups considerably influenced the electronic structures of the metal complexes, which altered the absorption profiles of the respective geometries, as demonstrated in this research. | - |
dc.identifier.bibliographicCitation | NANOMATERIALS, v.12, no.10, pp.1704 | - |
dc.identifier.doi | 10.3390/nano12101704 | - |
dc.identifier.issn | 2079-4991 | - |
dc.identifier.scopusid | 2-s2.0-85130144998 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/81699 | - |
dc.identifier.wosid | 000801903300001 | - |
dc.language | 영어 | - |
dc.publisher | MDPI | - |
dc.title | Near-Infrared Absorption Properties of Neutral Bis(1,2-dithiolene) Platinum(II) Complexes Using Density Functional Theory | - |
dc.type | Article | - |
dc.description.isOpenAccess | TRUE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied | - |
dc.relation.journalResearchArea | Chemistry; Science & Technology - Other Topics; Materials Science; Physics | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | platinum complex | - |
dc.subject.keywordAuthor | dithiolene complex | - |
dc.subject.keywordAuthor | NIR | - |
dc.subject.keywordAuthor | density functional theory | - |
dc.subject.keywordAuthor | GW-BSE approximation | - |
dc.subject.keywordPlus | TOTAL-ENERGY CALCULATIONS | - |
dc.subject.keywordPlus | DITHIOLENE COMPLEXES | - |
dc.subject.keywordPlus | OPTICAL-SPECTRA | - |
dc.subject.keywordPlus | METAL-COMPLEXES | - |
dc.subject.keywordPlus | NI | - |
dc.subject.keywordPlus | UREAS | - |
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