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DC Field | Value | Language |
---|---|---|
dc.citation.startPage | 159156 | - |
dc.citation.title | APPLIED SURFACE SCIENCE | - |
dc.citation.volume | 649 | - |
dc.contributor.author | Lee, Taewoong | - |
dc.contributor.author | Chae, Seongwook | - |
dc.contributor.author | Heo, Woo Sub | - |
dc.contributor.author | Kang, Haisu | - |
dc.contributor.author | Park, Jae Bin | - |
dc.contributor.author | Park, Yiseul | - |
dc.contributor.author | Park, Tae Hyun | - |
dc.contributor.author | Lee, Jin Hong | - |
dc.contributor.author | Lee, Seung Geol | - |
dc.date.accessioned | 2024-03-19T14:05:09Z | - |
dc.date.available | 2024-03-19T14:05:09Z | - |
dc.date.created | 2024-03-19 | - |
dc.date.issued | 2024-03 | - |
dc.description.abstract | Lithium - sulfur (Li-S) batteries with their high theoretical energy density and abundant resources have been considered as a promising candidate for next-generation energy storage systems. Nonetheless, undesirable diffusion of lithium polysulfides (LiPSs) toward the lithium metal anode in electrolytes during discharge/charge cycles of Li-S batteries, which is known as shuttle behavior of LiPSs, degrades the long-term stability of Li-S batteries and limits their practical applications. Herein, we present dye-functionalized carbonaceous interlayer, in which organic dye containing nitrogen and sulfur functional groups are incorporated into the carbon matrix of a graphitic layer via hydrothermal process. The introduction of such functional interlayer in Li-S batteries reveals that the carbon matrix with various heteroatom moieties can create physically/chemically favorable active sites for trapping LiPSs and enhance LiPSs conversion toward insoluble products of Li2S/Li2S2, resulting in excellent rate capability and long-term stability with high coulombic efficiency. This study emphasizes the potential of organic dyes functionalization and demonstrates enhanced LiPSs conversion and long-term stability of Li-S batteries. | - |
dc.identifier.bibliographicCitation | APPLIED SURFACE SCIENCE, v.649, pp.159156 | - |
dc.identifier.doi | 10.1016/j.apsusc.2023.159156 | - |
dc.identifier.issn | 0169-4332 | - |
dc.identifier.scopusid | 2-s2.0-85180400799 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/81672 | - |
dc.identifier.wosid | 001140308600001 | - |
dc.language | 영어 | - |
dc.publisher | ELSEVIER | - |
dc.title | Dye-functionalized carbonaceous interlayer as an efficient lithium polysulfide mediator for high performance lithium-sulfur batteries | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical; Materials Science, Coatings & Films; Physics, Applied; Physics, Condensed Matter | - |
dc.relation.journalResearchArea | Chemistry; Materials Science; Physics | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | Dye-functionalized interlayer | - |
dc.subject.keywordAuthor | Organic dyes | - |
dc.subject.keywordAuthor | Carbonaceous nanosheets | - |
dc.subject.keywordAuthor | Lithium -sulfur batteries | - |
dc.subject.keywordAuthor | Shuttle effect | - |
dc.subject.keywordPlus | ORGANIC FRAMEWORK | - |
dc.subject.keywordPlus | COMPOSITE | - |
dc.subject.keywordPlus | NANOSHEETS | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | ELECTRODE | - |
dc.subject.keywordPlus | NITROGEN | - |
dc.subject.keywordPlus | HOST | - |
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