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- Hong, Sung You
- Synthetic Organic Chemistry Lab.
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Air-, Moisture-Tolerant Nickel Catalysis and Regioselective Synthesis of Multi-Substituted Pyridines
- Author(s)
- Jeon, Jihwan, Hong, Sung You
- Issued Date
- 2022-04-15
- Citation
- 제129회 대한화학회 학술발표회
- Abstract
- Nickel(0)-catalyzed [2+2+2] cycloaddition reaction of 1,6-diynes and nitrile has been limited to air and moisture sensitive Ni(COD)2 system. Here in, we studied air and moisture sensitive Ni(0) system through in situ generation of Ni-Xantphos species. Our system afforded the complementary regioisomers. The origin of the regioselectivity was explained by frontier molecular orbital interactions with DFT calculation.
- Publisher
- 대한화학회
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