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Jo, Wook
Sustainable Functional Ceramics Lab.
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Can an Electric Field Induce an Antiferroelectric Phase Out of a Ferroelectric Phase?

Author(s)
Tan, XFrederick, J.Ma, C.Jo, WookRoedel, J.
Issued Date
2010-12
DOI
10.1103/PhysRevLett.105.255702
URI
https://scholarworks.unist.ac.kr/handle/201301/7562
Fulltext
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=78650273838
Citation
PHYSICAL REVIEW LETTERS, v.105, no.25
Abstract
It has been widely accepted that electric fields favor the ferroelectric phase with parallel electric dipoles over the antiferroelectric phase. With detailed measurements in polycrystalline ceramics of Pb(0.99)Nb(0.02)[(Zr(0.57)Sn(0.43))(1-y)Ti(y)](0.98)O(3), we demonstrate in this Letter that electric fields can induce an antiferroelectric phase out of a ferroelectric phase, i.e., trigger an apparently unlikely ferroelectric-to-antiferroelectric phase transition. We suggest that it is caused by the volume contraction from the converse piezoelectric effect at the coercive field with a reversed polarity.
Publisher
AMER PHYSICAL SOC
ISSN
0031-9007

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