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권영국

Kwon, Youngkook
Electrochemistry Lab for Energy and Environment
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dc.citation.conferencePlace US -
dc.citation.conferencePlace Virtual -
dc.citation.title 242nd ECS Meeting -
dc.contributor.author Kwon, Youngkook -
dc.date.accessioned 2024-01-31T20:05:55Z -
dc.date.available 2024-01-31T20:05:55Z -
dc.date.created 2022-12-11 -
dc.date.issued 2022-10-13 -
dc.description.abstract The efficient electrochemical conversion of CO2 to fuels or stock chemicals with high-energy density would be a major step forward in the introduction of a carbon neutral energy cycle. Especially, understanding the role of electrocatalysts, supports, and electrolytes that can efficiently reduce CO2 to fuels with high selectivity is a subject of significant interest. Copper is the only known catalyst for producing a reasonable quantity of hydrocarbons, which means that designing proper electrode interfaces would modulate the catalytic reactivity and product selectivity. One of the observations on copper catalyst interface is that copper catalyst with a specific atomic-scale gap accelerates the reaction kinetics and selectivity to C2+ products, by confining CO2 and reaction intermediates within a sub-nanoscale reactor in which the reaction energy for CO formation and subsequent C-C coupling can be accelerated. However, the selectivity control toward a target product such as ethylene or ethanol is a remaining issue to be resolved. Recently, we have designed interface rich CuO-Al2CuO4 catalyst and were able to reach about 80% FE of ethylene. In-situ ATR-FTIR and DFT calculation supported that CO2 was selectively converted to CO on CuO and subsequently CO was coupling on Al2CuO4 to ethylene. Therefore, designing interface rich catalysts offers efficient, yet cheap electrochemical CO2 reduction systems. -
dc.identifier.bibliographicCitation 242nd ECS Meeting -
dc.identifier.doi 10.1149/MA2022-02481863mtgabs -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/75402 -
dc.identifier.url https://iopscience.iop.org/article/10.1149/MA2022-02481863mtgabs -
dc.language 영어 -
dc.publisher ECS -
dc.title Interface Rich Catalyst Design for Enhanced CO2 Conversion -
dc.type Conference Paper -
dc.date.conferenceDate 2022-10-09 -

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