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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 6386 | - |
dc.citation.number | 13 | - |
dc.citation.startPage | 6379 | - |
dc.citation.title | NANOSCALE | - |
dc.citation.volume | 15 | - |
dc.contributor.author | Ahumada, Juan C. | - |
dc.contributor.author | Ahumada, Guillermo | - |
dc.contributor.author | Sobolev, Yaroslav | - |
dc.contributor.author | Kim, Minju | - |
dc.contributor.author | Grzybowski, Bartosz A. | - |
dc.date.accessioned | 2024-01-26T21:05:11Z | - |
dc.date.available | 2024-01-26T21:05:11Z | - |
dc.date.created | 2023-12-29 | - |
dc.date.issued | 2023-04 | - |
dc.description.abstract | In addition to modifying surface properties, self-assembled monolayers, SAMs, on nanoparticles can selectively incorporate small molecules from the surrounding solution. This selectivity has been used in the design of substrate-specific catalytic systems but its degree has not been quantified. This work uses catalytic centers embedded in on-nanoparticle hydrophobic SAMs to monitor and quantify the partitioning of molecules between the bulk solvent and these monolayers. A combination of experiments and theory allows us to relate the logarithm of the incorporation-into-SAM constant to the “bulk” log P values, characterizing the incoming substrates. These results are in line with classic, semi-empirical linear free energy relationships between partitioning solvent systems; in this way, they substantiate the view of nanoscopic on-particle SAMs acting akin to a bulk solvent phase. © 2023 The Royal Society of Chemistry. | - |
dc.identifier.bibliographicCitation | NANOSCALE, v.15, no.13, pp.6379 - 6386 | - |
dc.identifier.doi | 10.1039/d2nr06341g | - |
dc.identifier.issn | 2040-3364 | - |
dc.identifier.scopusid | 2-s2.0-85151027322 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/72426 | - |
dc.identifier.wosid | 000948916900001 | - |
dc.language | 영어 | - |
dc.publisher | Royal Society of Chemistry | - |
dc.title | On-nanoparticle monolayers as a solute-specific, solvent-like phase | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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