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DC Field | Value | Language |
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dc.citation.endPage | 8440 | - |
dc.citation.number | 23 | - |
dc.citation.startPage | 8433 | - |
dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.volume | 127 | - |
dc.contributor.author | Park, Jongnam | - |
dc.contributor.author | Koo, B | - |
dc.contributor.author | Yoon, KY | - |
dc.contributor.author | Hwang, Y | - |
dc.contributor.author | Kang, M | - |
dc.contributor.author | Park, JG | - |
dc.contributor.author | Hyeon, T | - |
dc.date.accessioned | 2023-12-22T10:36:26Z | - |
dc.date.available | 2023-12-22T10:36:26Z | - |
dc.date.created | 2014-10-06 | - |
dc.date.issued | 2005-06 | - |
dc.description.abstract | We synthesized uniform-sized nanorods of transition metal phosphides from the thermal decomposition of continuously delivered metal-phosphine complexes using a syringe pump. MnP nanorods with dimensions of 8 nm × 16 nm and 6 nm × 22 nm sized were synthesized by the thermal decomposition of Mn-TOP complex, which was prepared from the reaction of Mn2(CO)10 and tri-n-octylphosphine (TOP), using a syringe pump with constant injection rates of 10 and 20 mLVh, respectively. When Co-TOP complex, which was prepared from the reaction of cobalt acetylacetonate and TOP, was reacted in a mixture solvent composed of octyl ether and hexadecylamine at 300 °C using a syringe pump, uniform 2.5 nm × 20 nm sized Co2P nanorods were generated. When cobaltocene was employed as a precursor, uniform Co2P nanorods with 5 nm × 15 nm were obtained. When Fe-TOP complex was added to trioctylphosphine oxide (TOPO) at 360 °C using a syringe pump and then allowed to age at 360 °C for 30 min, uniform-sized FeP nanorods with an average dimension of 12 nm × 500 nm were produced. Nickel phosphide (Ni2P) nanorods with 4 nm × 8 nm were synthesized successfully by thermally decomposing the Ni-TOP complex, which was synthesized by reacting acetylacetonate [Ni(acac)2] and TOP. We measured the magnetic properties of these nanorods, and some of the nanorods exhibited different magnetic characteristics compared to the bulk counterparts. | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.127, no.23, pp.8433 - 8440 | - |
dc.identifier.doi | 10.1021/ja0427496 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.scopusid | 2-s2.0-20444503866 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/6943 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=20444503866 | - |
dc.identifier.wosid | 000229751100051 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Generalized synthesis of metal phosphide nanorods via thermal decomposition of continuously delivered metal-phosphine complexes using a syringe pump | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | SOURCE MOLECULAR PRECURSORS | - |
dc.subject.keywordPlus | MAGNETIC-PROPERTIES | - |
dc.subject.keywordPlus | SEMICONDUCTOR NANOWIRES | - |
dc.subject.keywordPlus | GOLD NANORODS | - |
dc.subject.keywordPlus | INORGANIC NANOCRYSTALS | - |
dc.subject.keywordPlus | SOLVENTLESS SYNTHESIS | - |
dc.subject.keywordPlus | MEDIATED SYNTHESIS | - |
dc.subject.keywordPlus | COBALT NANORODS | - |
dc.subject.keywordPlus | SINGLE-CRYSTAL | - |
dc.subject.keywordPlus | ZNS NANOWIRES | - |
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