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김영식

Kim, Youngsik
YK Research
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dc.citation.endPage 2775 -
dc.citation.number 9 -
dc.citation.startPage 2773 -
dc.citation.title INORGANIC CHEMISTRY -
dc.citation.volume 43 -
dc.contributor.author Kim, Youngsik -
dc.contributor.author Martin, SW -
dc.date.accessioned 2023-12-22T11:06:28Z -
dc.date.available 2023-12-22T11:06:28Z -
dc.date.created 2014-10-02 -
dc.date.issued 2004-05 -
dc.description.abstract he thioborate phase Ba7(BS3)4S was synthesized from solid state reaction and its crystal structure determined by single crystal X-ray diffraction analysis. It crystallizes in the monoclinic space group C2/c (No. 15) with a = 10.1750(15) A, b = 23.970(4) A, c = 10.1692(15) A, β = 90.095(2)°, and Z = 4. The structure consists of isolated trigonal planar (BS3)3- anions, and isolated S2- anions and Ba2+ cations. The additional sulfur anions have five-fold barium coordination, while the barium cations are coordinated by eight or nine sulfur atoms. Powder X-ray diffraction patterns from a bulk sample are compared to the calculated diffraction pattern from the single crystal structural analysis, and there is excellent agreement in general. The vibrational modes of the isolated (BS3)3- units were measured from Raman scattering and IR absorption spectra, and the frequencies agree very well with those found for similar orthothioborate phases. -
dc.identifier.bibliographicCitation INORGANIC CHEMISTRY, v.43, no.9, pp.2773 - 2775 -
dc.identifier.doi 10.1021/ic035454m -
dc.identifier.issn 0020-1669 -
dc.identifier.scopusid 2-s2.0-2142657867 -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/6869 -
dc.identifier.url http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=2142657867 -
dc.identifier.wosid 000221168000007 -
dc.language 영어 -
dc.publisher AMER CHEMICAL SOC -
dc.title Synthesis and crystal structure of barium thioborate Ba-7(BS3)(4)S -
dc.type Article -
dc.description.journalRegisteredClass scopus -

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