dc.citation.endPage |
2775 |
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dc.citation.number |
9 |
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dc.citation.startPage |
2773 |
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dc.citation.title |
INORGANIC CHEMISTRY |
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dc.citation.volume |
43 |
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dc.contributor.author |
Kim, Youngsik |
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dc.contributor.author |
Martin, SW |
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dc.date.accessioned |
2023-12-22T11:06:28Z |
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dc.date.available |
2023-12-22T11:06:28Z |
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dc.date.created |
2014-10-02 |
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dc.date.issued |
2004-05 |
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dc.description.abstract |
he thioborate phase Ba7(BS3)4S was synthesized from solid state reaction and its crystal structure determined by single crystal X-ray diffraction analysis. It crystallizes in the monoclinic space group C2/c (No. 15) with a = 10.1750(15) A, b = 23.970(4) A, c = 10.1692(15) A, β = 90.095(2)°, and Z = 4. The structure consists of isolated trigonal planar (BS3)3- anions, and isolated S2- anions and Ba2+ cations. The additional sulfur anions have five-fold barium coordination, while the barium cations are coordinated by eight or nine sulfur atoms. Powder X-ray diffraction patterns from a bulk sample are compared to the calculated diffraction pattern from the single crystal structural analysis, and there is excellent agreement in general. The vibrational modes of the isolated (BS3)3- units were measured from Raman scattering and IR absorption spectra, and the frequencies agree very well with those found for similar orthothioborate phases. |
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dc.identifier.bibliographicCitation |
INORGANIC CHEMISTRY, v.43, no.9, pp.2773 - 2775 |
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dc.identifier.doi |
10.1021/ic035454m |
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dc.identifier.issn |
0020-1669 |
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dc.identifier.scopusid |
2-s2.0-2142657867 |
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dc.identifier.uri |
https://scholarworks.unist.ac.kr/handle/201301/6869 |
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dc.identifier.url |
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=2142657867 |
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dc.identifier.wosid |
000221168000007 |
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dc.language |
영어 |
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dc.publisher |
AMER CHEMICAL SOC |
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dc.title |
Synthesis and crystal structure of barium thioborate Ba-7(BS3)(4)S |
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dc.type |
Article |
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dc.description.journalRegisteredClass |
scopus |
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