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| DC Field | Value | Language |
|---|---|---|
| dc.citation.endPage | 6045 | - |
| dc.citation.number | 17 | - |
| dc.citation.startPage | 6044 | - |
| dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
| dc.citation.volume | 131 | - |
| dc.contributor.author | Lee, Kyu Tae | - |
| dc.contributor.author | Kan, Wang H. | - |
| dc.contributor.author | Nazar, Linda F. | - |
| dc.date.accessioned | 2023-12-22T08:06:20Z | - |
| dc.date.available | 2023-12-22T08:06:20Z | - |
| dc.date.created | 2014-09-29 | - |
| dc.date.issued | 2009-06 | - |
| dc.description.abstract | Homogeneous-sized LiMPO4 (M = Fe, Mn) nanorods and bulk particles were synthesized, and the thermodynamic characteristics of their mixtures as electrodes were analyzed to study the lithiation/delithiation mechanism for the general case of nanoparticles with a heterogeneous particle size distribution. We show that ionic transport occurs between nano and bulk particles in a cell at equilibrium, due to their electrochemical potential difference that originates from their different thermodynamic properties. This means that one phase in a single particle is preferred to two phases in a single particle during lithiation/delithiation of LiMPO4 from the viewpoint of thermodynamics if the electrode is composed of differing particle sizes. | - |
| dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.131, no.17, pp.6044 - 6045 | - |
| dc.identifier.doi | 10.1021/ja8090559 | - |
| dc.identifier.issn | 0002-7863 | - |
| dc.identifier.scopusid | 2-s2.0-69949179164 | - |
| dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/6716 | - |
| dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=69949179164 | - |
| dc.identifier.wosid | 000265755800004 | - |
| dc.language | 영어 | - |
| dc.publisher | AMER CHEMICAL SOC | - |
| dc.title | Proof of Intercrystallite Ionic Transport in LiMPO4 Electrodes (M = Fe, Mn) | - |
| dc.type | Article | - |
| dc.description.journalRegisteredClass | scopus | - |
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